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HCOONa overset(350^(@))underset(Delta) t...

`HCOONa overset(350^(@))underset(Delta) to Gas(X) + Residue (Y)overset(CoCl_(3)) to "Complex" (Z)`
Complex (Z) is:

A

an outer orbital complex

B

optically active

C

oxidised when exposed to air

D

paramagnetic

Text Solution

Verified by Experts

The correct Answer is:
B

`HCOONaunderset(Delta)overset(350^(@)C)rarrH_(2)(X)+NaC_(2)O_(4)(Y)overset(CoCl_(3))rarrNa_(3)[Co(C_(2)O_(4))_3](Z)`
(i) `"Gas" (X) to H_(2)`
-It is diamagnetic
-B.O.=1
-It acts as `pi`-acid (into `sigma_(1s)^(**))`
(ii) `Na_(3)[Co(C_(2)O_(4))_3]`
`[M(AA)_(3)]`

Optically active
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