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Co^(2+)(aq)+SCN^(-)(aq) to "complex" (X)...

`Co^(2+)(aq)+SCN^(-)(aq) to "complex" (X)`.
`Ni^(2+)(aq)+"Dimethylglyoxime" overset(NH_(4)OH) to "Complex" (Y)`.
The coordination number of cobalt and nickel in complexes X and Y are four.
The IUPAC names of the complexes (X) and (Y) are respectively.

A

tetrahiocyanato-S-cobalt (II) and bis(dimethylglyoximate) nickel(II).

B

tetrathiocyanato-S-cobaltate (II) and bis(dimethylglyoximato) nickel (II).

C

tetrathiocyanato-S-cobaltate (II) and bis(dimethylglyoximato) nickelate(II).

D

tetrathiocyanato-S-cobaltate (II) and bis(dimethylglyoximato) nickel(II).

Text Solution

Verified by Experts

The correct Answer is:
B
`{:([X] to K_(2)[Ni(CN)_(4)],, B to K_(2)[overset(+2)(Ni)(DMG)_(2)]) , ("(Tetrahedral)" , "(Square planar)"), ("(spin free)" , "(spin paired)"), (d^(7) "," sp^(3), d^(8) "," dsp^(2)), (3u.p . e^(-)"(Paramag.)" , "(Dimag.)"):}`
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Co^(2+)(aq)+SCN^(-)(aq) to "complex" (X) . Ni^(2+)(aq)+"Dimethylglyoxime" overset(NH_(4)OH) to "Complex" (Y) . The coordination number of cobalt and nickel in complexes X and Y are four. The geometry of complexes (X) and (Y) are respectively :

Co^(2+)(aq)+SCN^(-)(aq) to "complex" (X) . Ni^(2+)(aq)+"Dimethylglyoxime" overset(NH_(4)OH) to "Complex" (Y) . The coordination number of cobalt and nickel in complexes X and Y are four. Select the correct statement for the complexes (X) and (Y).