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A metal complex Cr(NH(3))(4)Cl(2) having...

A metal complex `Cr(NH_(3))_(4)Cl_(2)` having molar conductivity corresponding to `1:1` electrolyte have been isolated in two Forms (X) and (Y), (X) reacts with `AgNO_(3)` giving white precipitate which turns yellow on reaction with sodium arsenite whereas (Y) gives a yellow precipitate soluble in concentrate `NH_(4)OH`
Which of the following statements is true for the complex (Y) ?

A

Its trans form is non-planar

B

Its IUPAC name is tetraaminedichloridochromate(III) bromide.

C

Its 'spin only' magnetic moment is 3.83 BM.

D

All of these

Text Solution

Verified by Experts

The correct Answer is:
C

`underset(d^(3))(X) to underset(d^(2)sp^(3))[Cr(NH_(3))_(4)ClBr]Cl,(Y) to underset(d^(2)sp^(3),mu=3.8 B.M.)[Cr(NH_(3))_(4)Cl_(2)]Br`
`"EAN" to 24-3+12=33`
Both X and Y can show G.I.
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