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Square planar complexes are generally fo...

Square planar complexes are generally formed by `d^(8)` ions with strong field ligands. The crystal field splitting is larger for second and third row transition elements and for more highly charged species. All the complexes having `4d^(8)" and "5d^(8)` configuration are mostly square including those with weak field ligands such halide ions. Square planar complexes with coordination number four can show diastereoisomerism.
Which one of the following square planar complexes will show geometrical isomerism ?

A

`[Pt(en)_(2)]^(2+)`

B

`[Pt(gly)_(2)]`

C

`[Pt(NH_(3))_(2)Cl(NH_(2)CH_(3))]Cl`

D

(b) and (c ) both

Text Solution

Verified by Experts

The correct Answer is:
D
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Square planar complexes are generally formed by d^(8) ions with strong field ligands. The crystal field splitting is larger for second and third row transition elements and for more highly charged species. All the complexes having 4d^(8)" and "5d^(8) configuration are mostly square including those with weak field ligands such halide ions. Square planar complexes with coordination number four can show diastereoisomerism. Amongst the following complexes which has square planar geometry ?

Square planar complexes are generally formed by d^(8) ions with strong field ligands. The crystal field splitting is larger for second and third row transition elements and for more highly charged species. All the complexes having 4d^(8)" and "5d^(8) configuration are mostly square including those with weak field ligands such halide ions. Square planar complexes with coordination number four can show diastereoisomerism. Which of the ions do not form the square planar complexes amongst the following ions ?

Square planar complexes are generally formed by d^(8) ions with strong field ligands. The crystal field splitting is larger for second and third row transition elements and for more highly charged species. All the complexes having 4d^(8)" and "5d^(8) configuration are mostly square including those with weak field ligands such halide ions. Square planar complexes with coordination number four can show diastereoisomerism. Which of the following staements is true for the complex [Ni(PPh_(3))_(2)Br_(2)] ?

Which of the following are square planar complexes

Which of the following square planar complexes will form two geometrical isomers?