Home
Class 12
CHEMISTRY
Select the total number of properties wh...

Select the total number of properties which are correct with respect to
`K_(4)[Fe(CN)_(5)O_(2)]` or any of its isomers (`d^(6)` configuration of central metal ion).
(a) Paramagnetic
(b) Inner orbital complex
(c ) Low spin complex
(d)`Delta_(0) gt P`
(e ) Shows optical isomerism
(f) Shows linkage isomerism

Text Solution

Verified by Experts

The correct Answer is:
6
`overset(+4)K_(4)[overset(+2)(Fe)(overset(-5)(CN))_(5)overset(-1)O_(2)],(a),(b),(c ),(d),(e ),(g)`
Also, consider linkage isomers for (e ).
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise MATCH THE COLUMN TYPE|41 Videos

  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise Subjective Type|63 Videos

  • D-BLOCK ELEMENTS

    GRB PUBLICATION|Exercise Subjective Type|18 Videos

Similar Questions

Explore conceptually related problems

Which of the following statement is correct for the complex K_(4)[Fe(CN)_(5)O_(2)] ? [Fe having t_(2g)^(6)e_(g^(0)) configuration ]

Which of the following statement is correct for the complex Ca_(2)[Fe(CN)_(5)O_(2)] having t_(2g)^(6),e_(g)^(0) electronic configuration ? .

Which one of the following statements are correct for the complex [Co(NH_(3))_(4)(Cl)(NO_(2))]Cl ? (P) Cobalt is in +III oxidation state involving d^(2)sp^(3) hybridization. (Q) Cobalt is in +III oxidation state involving sp^(3)d^(2) hybridization. (R ) It shows ionisation as well as linkage isomerism. (S) It also shows geometrical isomerism.

Square planar complexes are formed by d^(8) ions with strong field ligands The crystal field splitting Delta_(0) is larger for the second and theird row transition elements and for more highly charged species All the complexes having 4d^(8) and 5d^(8) configurations are mostly square planar including those with weak field ligands such as halide ions square planar complexes can show geometrical isomerism but they do not show optical isomerism due to the presence of plane of symmetry (a) All are low spin complexes (b) [Ni(CO)_(4)] (c) [Pt(NH_(3))_(4)]^(2+) (d) [Ni(NH_(3))_(6)]^(2+) .

Square planar complexes are formed by d^(8) ions with strong field ligands The crystal field splitting Delta_(0) is larger for the second and theird row transition elements and for more highly charged species All the complexes having 4d^(8) and 5d^(8) configurations are mostly square planar including those with weak field ligands such as halide ions square planar complexes can show geometrical isomerism but they do not show optical isomerism due to the presence of plane of symmetry Among the following complexes which has a square planar geometry? (a) [RhCI(CO)(PPh_(3))_(2)] (b) K_(3)[Cu(CN)_(4)] (c ) [Ni(CO)_(4)] (d) K_(2)[Zn(CN)_(4)] .

Number of the following statements is/are correct? (A) Greater the stability constant of a complex ion, greater is its stability (B) Greater the oxidation state of the central metal ion, greater is the stability of the complex (C ) CO stabilises complex becuase of its synergic Bonding. (D) Chelate complexes have low stability constants

Square planar complexes are formed by d^(8) ions with strong field ligands The crystal field splitting Delta_(0) is larger for the second and theird row transition elements and for more highly charged species All the complexes having 4d^(8) and 5d^(8) configurations are mostly square planar including those with weak field ligands such as halide ions square planar complexes can show geometrical isomerism but they do not show optical isomerism due to the presence of plane of symmetry Which of the following molecule has synergic bonding? (a) [Fe(pi -C_(5)H_(5))_(2)] (b) [RhCI(PPh_(3))_(3)]^(3+) (c) [Fe(Phen)_(3)]^(3+) (d) All are having synergic bonding .

GRB PUBLICATION-COORDINATION COMPOUNDS-SBJECTIVE TYPE
  1. Find the number of species having C-O bond length grater than that in ...

    Text Solution

    |

  2. Consider the complex [Co(NH(3))(4)CO(3)]ClO(4), in which coordination ...

    Text Solution

    |

  3. Select the total number of properties which are correct with respect t...

    Text Solution

    |

  4. How many of the following obey's Sidgwick EAN rule ? (a) K(4)[Fe(CN)...

    Text Solution

    |

  5. How many of the following compounds splitting energy (Delta) is greate...

    Text Solution

    |

  6. For what minimum value of n, polymerisation isomers of [Fe(NH(3))(3)(N...

    Text Solution

    |

  7. If the complex [Mo(CO)(4) Br(CPh(3))] follow 18 electron rule or EAN r...

    Text Solution

    |

  8. Find the total number of compounds/ions having linear shape. [Ag(CN)...

    Text Solution

    |

  9. Find the total number of diastereomers of the complex M(a(2)b(2)c(2)) ...

    Text Solution

    |

  10. Find the number of complexes involving d^(2)sp^(3) hybridisation of th...

    Text Solution

    |

  11. Find the total number of compounds or ions having O-O bond longer than...

    Text Solution

    |

  12. Find the total number of Fe-Fe bonds in Fe(3)(CO)(12) if it follows EA...

    Text Solution

    |

  13. Find the number of Be-vecy-Be bond angles(s) in above structure.

    Text Solution

    |

  14. How many of the following are square palanar? (a) Ni(dmg)(2)" "(b)...

    Text Solution

    |

  15. Consider the complex [Pt(S(5))(3)]^(2-). If x, y and z are the number ...

    Text Solution

    |

  16. Find the total number of complexes / species which are paramagnetic. ...

    Text Solution

    |

  17. A symmetricla bridged complex cation made of Co(III), NH(3) molecules ...

    Text Solution

    |

  18. In sodium nitroprusside the oxidation number, coordination number and ...

    Text Solution

    |

  19. Give the co-ordination number of La in the compound Na[La EDTA (H(2)O)...

    Text Solution

    |

  20. Find the number of molecules in which pi-d o n a t io n is present ...

    Text Solution

    |