Home
Class 12
CHEMISTRY
If the complex [Mo(CO)(4) Br(CPh(3))] fo...

If the complex `[Mo(CO)_(4) Br(CPh_(3))]` follow 18 electron rule or EAN rule, find the bond order of Mo-C bond .

Text Solution

Verified by Experts

The correct Answer is:
3

`[overset(+2)(Mo)(overset(0)CO)_(4)overset(-1)(Br)(CP overset(-1" ")(h_(3)))]`
`impliesd^(4),2+4+4x=18`
`implies" " x=3`
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise MATCH THE COLUMN TYPE|41 Videos
  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise Subjective Type|63 Videos
  • D-BLOCK ELEMENTS

    GRB PUBLICATION|Exercise Subjective Type|18 Videos

Similar Questions

Explore conceptually related problems

Find the bond order of CO

Complex following EAN rule is

Which of the following complex obeys EAN rule ?

Which of the following complexes follow EAN rule ?

The value of x in the complex H_(x)Co(CO)_(4) , on the basis of E.A.N. rule is (At. No. Co = 27)

The realtive stabilities of metal carbonyls and their ions can be explained on the basis of a rule which is known as 18e^(-) rule. If number of valence shell electrons of the metal + number of electrons donated by bonded CO groups comes to be 18 electrons, then carbonyl is said to be stable. Some heteroleptic/noncarbonyl complexes also follow 18 electron rule. Identify the number of complexes following the rule. [Mn(CO)_(5)], [Co(CO)_(4)] [(eta^(5)-C_(5)H_(5))_(2)Fe] , [(CO)_(5)(PF_(3))]^(+), [(eta^(5)-C_(5)H_(5)) [Cr(NO)_(4)], Fe(CO)_(2)Cl] , [Fe(CO)_(2)(NO)_(2)], [Fe(CO)_(5)], [Mn_(2)(CO)_(10)]

GRB PUBLICATION-COORDINATION COMPOUNDS-SBJECTIVE TYPE
  1. How many of the following compounds splitting energy (Delta) is greate...

    Text Solution

    |

  2. For what minimum value of n, polymerisation isomers of [Fe(NH(3))(3)(N...

    Text Solution

    |

  3. If the complex [Mo(CO)(4) Br(CPh(3))] follow 18 electron rule or EAN r...

    Text Solution

    |

  4. Find the total number of compounds/ions having linear shape. [Ag(CN)...

    Text Solution

    |

  5. Find the total number of diastereomers of the complex M(a(2)b(2)c(2)) ...

    Text Solution

    |

  6. Find the number of complexes involving d^(2)sp^(3) hybridisation of th...

    Text Solution

    |

  7. Find the total number of compounds or ions having O-O bond longer than...

    Text Solution

    |

  8. Find the total number of Fe-Fe bonds in Fe(3)(CO)(12) if it follows EA...

    Text Solution

    |

  9. Find the number of Be-vecy-Be bond angles(s) in above structure.

    Text Solution

    |

  10. How many of the following are square palanar? (a) Ni(dmg)(2)" "(b)...

    Text Solution

    |

  11. Consider the complex [Pt(S(5))(3)]^(2-). If x, y and z are the number ...

    Text Solution

    |

  12. Find the total number of complexes / species which are paramagnetic. ...

    Text Solution

    |

  13. A symmetricla bridged complex cation made of Co(III), NH(3) molecules ...

    Text Solution

    |

  14. In sodium nitroprusside the oxidation number, coordination number and ...

    Text Solution

    |

  15. Give the co-ordination number of La in the compound Na[La EDTA (H(2)O)...

    Text Solution

    |

  16. Find the number of molecules in which pi-d o n a t io n is present ...

    Text Solution

    |

  17. Oxidation number of the central iron atom in the complex Fe(4)[Fe(CN)(...

    Text Solution

    |

  18. Find the EAN value of cetral atom of ferrocene [Fe(pi-C(5)H(5))(2)]

    Text Solution

    |

  19. If EAN of central metal ion X^(2+) in a non-chelating complex is 34 an...

    Text Solution

    |

  20. Find the change of EAN values when the complex (A) is changing into (B...

    Text Solution

    |