Home
Class 12
CHEMISTRY
Find the number of complexes following s...

Find the number of complexes following sidgwick EAN rule :
`[Ag(CN)_(2)^(-)," "[HgI_(4)]^(2-),`
`[Ti(CO)_(6)]^(2-)," "[Ti(sigma-C_(5)H_(5))_(2)(pi-C_(5)H_(5))_(2)]^(@),`
`[Fe(CN)_(6)NO]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
2
`[Ag(CN)_(2)]^(-) implies47-1+4=50 xx`
`[HgI_(4)]^(2-) implies22-2+8=86 right`
`[Ti(CO)_(6)]^(2-) implies22+2+12=36 right`
`[Ti(sigma-C_(5)H_(5))_(2)(pi-C_(5)H_(5))_(2)] implies22-4+4+12=34 xx`
`[overset(+3)Fe(overset(-6)CN)_(6)overset(+)NO]^(2-)implies26-3+12=35 xx`
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    GRB PUBLICATION|Exercise MATCH THE COLUMN TYPE|41 Videos

  • CHEMICAL KINETICS

    GRB PUBLICATION|Exercise Subjective Type|63 Videos

  • D-BLOCK ELEMENTS

    GRB PUBLICATION|Exercise Subjective Type|18 Videos

Similar Questions

Explore conceptually related problems

IUPA name for [Fe(CO)_(2)(sigma-C_(5)H_(5))(pi -C_(5)H_(5))] complex :

Find the number of complexes which follow sidgwick rule of EAN [Fe(CO)_(5)]," "[Mn(CO)_(5)]," "[NiCl_(4)]^(2-) , [Pt(NH_(3))_(4)Cl_(2)]^(2+)," "[HgI_(4)]^(2-)," "H[AuCl_(4)] Atomic number : Fe = 26, Mn = 25, Ni = 28, Pt = 78, Hg = 80, Au = 79

H_(2)O_(2) reduces K_(4)Fe(CN)_(6)

Select the correct IUPAC name for [Ti (pi - C_(5)H_(5))_(2)(O -C_(5)H_(5))_(2)] .

Find the difference in EAN of the complexes : [Ti(sigma-C_(5)H_(5))_(2)(pi-C_(5)H_(5))_(2)]" and "[Cr(C_(6)H_(6))_(2)]

How many of the following obey's Sidgwick EAN rule ? (a) K_(4)[Fe(CN)_(6)]," "(b) K_(3)[Fe(CN)_(6)] , (c ) Mn_(2)(CO)_(10)," "(d) [Fe(H_(2)O)_(5)NO]SO_(4) , (e ) Na_(2)[Fe(CN)_(5)NO]," "(f) [Co_(2)(CO)_(8)] , (g) [Fe(pi-C_(5)H_(5))_(2)]

GRB PUBLICATION-COORDINATION COMPOUNDS-SBJECTIVE TYPE
  1. What is the difference between the EAN value of central metla ion in N...

    Text Solution

    |

  2. Find the difference in the EAN value, if the NO ligand is considered a...

    Text Solution

    |

  3. Find the number of complexes following sidgwick EAN rule : [Ag(CN)(2...

    Text Solution

    |

  4. If EAN of metal is 36 in [M(CO)(2)(sigma-C(5)H(5))(pi-C(5)H(5))] F...

    Text Solution

    |

  5. Find number of Co-N linkage in pentaammine cobalt(III)-mu-amidodiammin...

    Text Solution

    |

  6. Write simplest ratio of Co^(3+) : NH(3) : NO(2)^(-) in : tetraamminedi...

    Text Solution

    |

  7. How many moles of ions (cation and anion) are present in 1 mole of Dia...

    Text Solution

    |

  8. Find the total number of stereoisomers of [M(gly)(3)] [Where M is an...

    Text Solution

    |

  9. Find the number of diamagnetic complexes which show geometrical isomer...

    Text Solution

    |

  10. Among the following, total number of species is/are existing as optica...

    Text Solution

    |

  11. Consider the complexes (P) [Fe(Cl)(F)(CN)(H(2)O)(en)] (Q) [MoCl(2)...

    Text Solution

    |

  12. In the given following complex compound / ions, how many exist in enan...

    Text Solution

    |

  13. (1)/(4)[Li(CH(3))(4)]+[Mo(CO)(6)] to [X] Here X is Lithium acetylpen...

    Text Solution

    |

  14. Find the total number of geometrical iosmers of [M(AB)(CD)(EF)]^(n+)

    Text Solution

    |

  15. Find the number of geometrical isomer of Ma(2)bcde which have identica...

    Text Solution

    |

  16. Find the maximum number of atoms in one plane in [Fe(CN)(6)]^(3-)

    Text Solution

    |

  17. Find the number of unpaired electrons in e(g) orbital of Fe in K(4)[Fe...

    Text Solution

    |

  18. Find the number of unpaired electrons in Pentaaquanitrosyliumiron(I) s...

    Text Solution

    |

  19. Find the change in magnetic moment when [Ni(H(2)O)(6)]^(2+) is convert...

    Text Solution

    |

  20. How many non-axial d-orbitals are involved in hybridisation of CrO(2)C...

    Text Solution

    |