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In octahedral complex Ma(2)b(2)cd, total...

In octahedral complex `Ma_(2)b_(2)cd`, total number of steroisomers is

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To determine the total number of stereoisomers for the octahedral complex \( Ma_2b_2cd \), we need to analyze the arrangement of the ligands around the central metal atom \( M \). ### Step-by-Step Solution: 1. **Identify the Coordination Number and Geometry**: - The complex \( Ma_2b_2cd \) has a coordination number of 6, which corresponds to an octahedral geometry. 2. **Determine the Types of Ligands**: - The complex consists of two types of bidentate ligands \( A \) and \( B \), and two monodentate ligands \( C \) and \( D \). 3. **Geometric Isomerism**: - In octahedral complexes, geometric isomers can arise from different arrangements of the ligands. For \( Ma_2b_2cd \), we can have: - **Facial (fac)**: where the two \( A \) ligands and the two \( B \) ligands occupy adjacent positions. - **Meridional (mer)**: where the two \( A \) ligands and the two \( B \) ligands occupy positions such that they are opposite each other. 4. **Counting Geometric Isomers**: - For \( Ma_2b_2cd \): - **Facial Isomer**: The arrangement can be \( AABBCD \). - **Meridional Isomer**: The arrangement can be \( AABCD \). - Thus, there are 2 geometric isomers. 5. **Optical Isomerism**: - Optical isomers arise when a complex lacks a plane of symmetry. - The facial isomer can have optical isomers because it lacks symmetry. - The meridional isomer typically has a plane of symmetry and does not exhibit optical isomerism. 6. **Total Stereoisomers**: - From the facial isomer, we can have 2 optical isomers (enantiomers). - From the meridional isomer, we have 1 non-optical isomer. - Therefore, the total number of stereoisomers is \( 2 \) (from facial) + \( 1 \) (from meridional) = **3 stereoisomers**. ### Final Answer: The total number of stereoisomers for the octahedral complex \( Ma_2b_2cd \) is **3**.

To determine the total number of stereoisomers for the octahedral complex \( Ma_2b_2cd \), we need to analyze the arrangement of the ligands around the central metal atom \( M \). ### Step-by-Step Solution: 1. **Identify the Coordination Number and Geometry**: - The complex \( Ma_2b_2cd \) has a coordination number of 6, which corresponds to an octahedral geometry. 2. **Determine the Types of Ligands**: ...
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Write the sum of geometrical isomers in [Ma_(2)b_(2)c_(2)] complex and stereoisomers in [M(AB)_(3)] complex .

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Knowledge Check

  • Co-ordination complexes can show stereoisomerism square planar complexes of Ma_(2)b_(2) type can show geometrical isomerism but not optical & octahedral complexes of Ma_(2)b_(2)C_(2), Ma_(3)b_(3) Mabcdef etc show stereoisomerism, for e.g. Mabcdef have 15 geometrical isomers & all are optically active so it has 15 pairs of enantiomers thus in totaly it has 30 stereoisomers. (a,b,c,d etc. are monodentate lignads while AB is bidenatate ligand) How many pair of enantiomers exits for Ma_(2)b_(2)c_(2) ?

    A
    0
    B
    2
    C
    1
    D
    4
  • Co-ordination complexes can show stereoisomerism square planar complexes of Ma_(2)b_(2) type can show geometrical isomerism but not optical & octahedral complexes of Ma_(2)b_(2)C_(2), Ma_(3)b_(3) Mabcdef etc show stereoisomerism, for e.g. Mabcdef have 15 geometrical isomers & all are optically active so it has 15 pairs of enantiomers thus in totaly it has 30 stereoisomers. (a,b,c,d etc. are monodentate lignads while AB is bidenatate ligand) Which of the following can show geometrical as well as optical isomerism?

    A
    `M(AB)_(3)`
    B
    `Mabcd` (tetrahedral)
    C
    `Ma_(3)b_(3)`
    D
    `Ma_(4)b_(2)`
  • An octahedral complex having formula Ma_(2)b_(2)C_(2) , which of the following combination is possible to exhibitd optical isomerism

    A
    `a = Cl^(-) " " B "&" C = (en)`
    B
    a & b & `c = EDTA`
    C
    a & `b = C_(2)O_(4)^(-2), " " c = en`
    D
    `a = H_(2)O, b = NH_(3), C = Cl^(-)`
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    A metal complex of coordination number six having three different types of ligands a, b and c of composition Ma_(2)b_(2)c_(2) can exist in several geometrical isomeric forms, the total number of such isomers is:

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