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In octahedral complex Ma(2)b(2)cd, total...

In octahedral complex `Ma_(2)b_(2)cd`, total number of steroisomers is

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To determine the total number of stereoisomers for the octahedral complex \( Ma_2b_2cd \), we need to analyze the arrangement of the ligands around the central metal atom \( M \). ### Step-by-Step Solution: 1. **Identify the Coordination Number and Geometry**: - The complex \( Ma_2b_2cd \) has a coordination number of 6, which corresponds to an octahedral geometry. 2. **Determine the Types of Ligands**: - The complex consists of two types of bidentate ligands \( A \) and \( B \), and two monodentate ligands \( C \) and \( D \). 3. **Geometric Isomerism**: - In octahedral complexes, geometric isomers can arise from different arrangements of the ligands. For \( Ma_2b_2cd \), we can have: - **Facial (fac)**: where the two \( A \) ligands and the two \( B \) ligands occupy adjacent positions. - **Meridional (mer)**: where the two \( A \) ligands and the two \( B \) ligands occupy positions such that they are opposite each other. 4. **Counting Geometric Isomers**: - For \( Ma_2b_2cd \): - **Facial Isomer**: The arrangement can be \( AABBCD \). - **Meridional Isomer**: The arrangement can be \( AABCD \). - Thus, there are 2 geometric isomers. 5. **Optical Isomerism**: - Optical isomers arise when a complex lacks a plane of symmetry. - The facial isomer can have optical isomers because it lacks symmetry. - The meridional isomer typically has a plane of symmetry and does not exhibit optical isomerism. 6. **Total Stereoisomers**: - From the facial isomer, we can have 2 optical isomers (enantiomers). - From the meridional isomer, we have 1 non-optical isomer. - Therefore, the total number of stereoisomers is \( 2 \) (from facial) + \( 1 \) (from meridional) = **3 stereoisomers**. ### Final Answer: The total number of stereoisomers for the octahedral complex \( Ma_2b_2cd \) is **3**.

To determine the total number of stereoisomers for the octahedral complex \( Ma_2b_2cd \), we need to analyze the arrangement of the ligands around the central metal atom \( M \). ### Step-by-Step Solution: 1. **Identify the Coordination Number and Geometry**: - The complex \( Ma_2b_2cd \) has a coordination number of 6, which corresponds to an octahedral geometry. 2. **Determine the Types of Ligands**: ...
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Write the sum of geometrical isomers in [Ma_(2)b_(2)c_(2)] complex and stereoisomers in [M(AB)_(3)] complex .

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A metal complex of coordination number six having three different types of ligands a, b and c of composition Ma_(2)b_(2)c_(2) can exist in several geometrical isomeric forms, the total number of such isomers is:

GRB PUBLICATION-COORDINATION COMPOUNDS-SBJECTIVE TYPE
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