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Colligative properties i.e., the propert...

Colligative properties i.e., the properties of solution which depend upon the particles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and relative lowering of vapour pressure. Experimental values of colligative properties for electrolytes are always higher than those obtained theoreticallu. The ratio of experimental colligative properties to theoretical colligative properties is called as van't Hoff factor (i).
A weak monoprotic acid (molar mass `= 180`) aqeous solution of `0.18%` w/v at `300 K` has observed osmoles pressure `0.369` atm. What should be its van't Hoof factor(i) `(R = 0.082 atm xx L//K//"mole")` ?

A

`1.2 `

B

`1.5 `

C

`1`

D

`0.5`

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The correct Answer is:
B
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Colligative properties i.e., the properties of solution which depend upon the particles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and relative lowering of vapour pressure. Experimental values of colligative properties for electrolytes are always higher than those obtained theoreticallu. The ratio of experimental colligative properties to theoretical colligative properties is called as van't Hoff factor (i). What is observed molar mass of weak acid in soluton in above equation?

Colligative properties i.e., the properties of solution which depend upon the particles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and relative lowering of vapour pressure. Experimental values of colligative properties for electrolytes are always higher than those obtained theoreticallu. The ratio of experimental colligative properties to theoretical colligative properties is called as van't Hoff factor (i). If equal volume of 0.01 M Ma OH is added in the solution of above weak acid solution then what will be new observed osmotic pressure at same temperature? Neglect the hydrolysis, dissociation of water and any volume concentration or expansion. Assume 10% dissociation of salt formed.

Colligative properties|Relative lowering of vapour pressure

Colligative properties of the solution depend upon :

Colligative properties i.e., the properties of solution which depends upon the number pf aprticles present in solution are osmotic pressure, depression in freezing point, elevation in boiling point and lowering in vapour pressure. Experimental values of colligative properties for electroetically because electrolytes dissociates to furnish more ions in solution. On the other hand experimentally obtained values of colligative properties for associating nature of solute ate lower than those obtained theoretically. The ratio of experimantal colligative properties to theoretical colligative properties is called as van't Hoff factor (i) . For 1M solution of HA having alpha gt 0.05 , the dissociation constant K_(a) in terms of van't Hoff factor (i) can be written as :

Colligative Properties: Osmotic pressure, Vant Hoff factor.

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