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During the electrolysis of 0.1 M CuSO(4)...

During the electrolysis of 0.1 M `CuSO_(4)` solution using coppepr electrodes, a depletion of `[Cu^(2+)]` occurs near the cathode with a corresponding excess near the anode, owing to inefficient stirring of the solution. If the local concentration of `[Cu^(2+)]` near the anode and cathode are respectively 0.12 M and 0.08 M, calcualte the back emf developed. Temperature = 298 K.

A

22 mV

B

5.2 mV

C

29 mV

D

59 mV

Text Solution

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The correct Answer is:
B
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