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A mixture contaning 0.05 moleof K(2)Cr(2...

A mixture contaning 0.05 moleof `K_(2)Cr_(2)O_(7) and 0.02 "mole of" KMnO_(4)` was treated eoith excess of KI in acidic medium. The liberated iodine required `1.0L "of" Na_(2)S_(2)O_(3)` solution for titration. Concentration of `Na_(2)S_(2)O_(3)` solution was:

A

`0.4 molL^(-1)`

B

`0.20 molL^(-1)`

C

`0.25 molL^(-1)`

D

`0.30 molL^(-1)`

Text Solution

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The correct Answer is:
A
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0.5 gmixture of K_(2)Cr_(2)O_(7) and KMnO_(4) was treated with excess of KI in acidic medium. Iodine liberated required 150 cm^(3) of 0.10 N solution of thiosulphate solution for titration. Find trhe percentage of K_(2)Cr_(2)O_(7) in the mixture :

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