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An impure sample of sodium oxalate (Na(2...

An impure sample of sodium oxalate `(Na_(2)C_(2)O_(4)` weighing 0.20 g is dissolved in aqueous solution of `H_(2)SO_94)` and solution is titrated at `70^(@)C`,requiring 45 mL of 0.02 M `KMnO_(4)` solution. The end point is overrun, and back titration in carried out with 10 mL of 0.1 M oxalic acid solution.Find the purity of `Na_(2)C_(2)O_(4)` in sample:

A

75

B

83.75

C

90.25

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
B
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NARENDRA AWASTHI-STOICHIOMETRY-Level 2 (Q.1 To Q.30)
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  4. 11.6 g of an organic compound having formula (C(n)H(2n+2)) is burnt in...

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  5. H(2)O(2)+2KIoverset(40% "yield")rarrI(2)+2KOH H(2)O(2)+2KMnO(4)+3H(2...

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  8. 20 mL of 0.2 M NaOH(aq) solution is mixed with 35 mL of this 0.1 ML N...

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  14. 20 mL of 0.1 M solution of compound NaCO(3).NaHCO(3).2H(2)O is titrate...

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  16. A mixture of FeO and Fe(2)O(3) is completely reacted with 100 mL of 0...

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  18. 0.10 g of a sample containing CuCO(3) and some inert impurity was diss...

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  19. 1 mole of equimolar mixture of ferric oxalate and ferrous oxalate requ...

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  20. An impure sample of sodium oxalate (Na(2)C(2)O(4) weighing 0.20 g is d...

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