Home
Class 11
CHEMISTRY
If hydrogen atoms (in the ground state )...

If hydrogen atoms (in the ground state ) are passed through an homogeneous magnetic field, the beam is split into two parts. This interaction with the magnetic field shows that the atoms must have magnetic moment. However, the moment cannot be due to the orbital angular momentum since l=0. Hence one must assume existence of intrinsic angular momentum, which as the experiment shows, has only two permitted orientations.
Spin of the electron produce angular momentum equal to `S=sqrt(s(s+1))(h)/(2pi)` where `S=+(1)/(2)`.
Total spin of an atom =`+(n)/(2) " or "-(n)/(2)`
where n is the number of unpaired electrons.
The substance which contain species with unpaired electrons in their orbitals behave as paramagnetic substances. The paramagnetism is expressed in terms of magnetic moment. The magnetic moment of an atom
`mu_(s)sqrt(s(s+1))(eh)/(2pimc)=sqrt((n)/(2)((n)/(2)+1))(eh)/(2pimc)" "s=(n)/(2)`
`impliesmu_(s)=sqrt(n(n+1))` B.M.
1. B.M. (Bohr magneton)=`(eh)/(4pimc)`
If magnetic moment is zero the substance is diamagnetic.
Which of the following ion has lowest magnetic moment?

A

`Fe^(2+)`

B

`Mn^(2+)`

C

`Cr^(3+)`

D

`V^(3+)`

Text Solution

Verified by Experts

Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    NARENDRA AWASTHI|Exercise Level 2|1 Videos

Similar Questions

Explore conceptually related problems

If hydrogen atoms (in the ground state ) are passed through an homogeneous magnetic field, the beam is split into two parts. This interaction with the magnetic field shows that the atoms must have magnetic moment. However, the moment cannot be due to the orbital angular momentum since l=0. Hence one must assume existence of intrinsic angular momentum, which as the experiment shows, has only two permitted orientations. Spin of the electron produce angular momentum equal to S=sqrt(s(s+1))(h)/(2pi) where S=+(1)/(2) . Total spin of an atom = +(n)/(2) " or "-(n)/(2) where n is the number of unpaired electrons. The substance which contain species with unpaired electrons in their orbitals behave as paramagnetic substances. The paramagnetism is expressed in terms of magnetic moment. The magnetic moment of an atom mu_(s)sqrt(s(s+1))(eh)/(2pimc)=sqrt((n)/(2)((n)/(2)+1))(eh)/(2pimc)" "s=(n)/(2) impliesmu_(s)=sqrt(n(n+1)) B.M. 1. B.M. (Bohr magneton)= (eh)/(4pimc) If magnetic moment is zero the substance is diamagnetic. If an ion of _(25)Mn has a magnetic moment of 3.873 B.M. Then oxidation state of Mn in ion is :

Which of the following ions show higher spin only magnetic moment value?

The complex showing a spin - only magnetic moment

NARENDRA AWASTHI-ATOMIC STUCTURE-Exercise
  1. One of the fundamental laws of physics is that matter is most stable w...

    Text Solution

    |

  2. One of the fundamental laws of physics is that matter is most stable w...

    Text Solution

    |

  3. If hydrogen atoms (in the ground state ) are passed through an homogen...

    Text Solution

    |

  4. If hydrogen atoms (in the ground state ) are passed through an homogen...

    Text Solution

    |

  5. Ozone in the upper atmoshphere absorbs ultraviolet radiation which ind...

    Text Solution

    |

  6. Ozone in the upper atmoshphere absorbs ultraviolet radiation which ind...

    Text Solution

    |

  7. The existence of negatively charged particle in an atom was shown by J...

    Text Solution

    |

  8. The existence of negatively charged particle in an atom was shown by J...

    Text Solution

    |

  9. The existence of negatively charged particle in an atom was shown by J...

    Text Solution

    |

  10. Select the correct statemtnt (s):

    Text Solution

    |

  11. The angular momentum of electron can have the value (s) :

    Text Solution

    |

  12. Select incorrect statement (s) :

    Text Solution

    |

  13. Select theh correct statement (s) :

    Text Solution

    |

  14. Choose the correct statement (s) :

    Text Solution

    |

  15. For radial probability curves. Which of the following is/are correct ?

    Text Solution

    |

  16. Choose the incorrect statement (s) :

    Text Solution

    |

  17. Choose the correct statements among the following :

    Text Solution

    |

  18. Select the correct statement (s) regarding 3p(y) orbitl :

    Text Solution

    |

  19. Select the correct statement (s) :

    Text Solution

    |

  20. Hydrogen has :

    Text Solution

    |