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van't Hoff proved that osmotic pressure ...

van't Hoff proved that osmotic pressure (`pi`) is a colligative property. For an ideal solution, osmotic pressure(`pi`) is helpful to determine that molecular mass of solute using `M_(B)=(W_(B)RT)/(pi.V)` Relation can exxpressed by the curve (C = concentration) :

A

B

C

D

Text Solution

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Assertion. Out of various colligative properties, osmotic pressure is used for determination of molecular masses of polymers.

What is the advantage of using osmotic pressure as com-ared to other colligative properties in determining molar mass of a solute ?

Knowledge Check

  • The osmotic pressure (pi) of a solution is given by reation

    A
    `pi = (RT)/C`
    B
    `pi = (CT)/R`
    C
    `pi = (RC)/T`
    D
    `pi/C =RT`
  • Assertion: Osmotic pressure is a colligative property. Reason: Osmotic pressure of a solution at any temperature T depends on the molar concentration.

    A
    Both A and R are true and R is the correct explanation of A
    B
    Both A and R are true but R is not a correct explanation of A
    C
    A is true but R is false
    D
    A is false but R is true
  • At constant temp. the osmotic pressure (pi) and the molarity (M) of the solution are related as

    A
    `pi prop M`
    B
    `pi prop 1/M`
    C
    `pi prop sqrt(M)`
    D
    `pi prop 1/sqrt(M)`
  • Similar Questions

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    (i) Prove that osmotic pressure is a colligative property. (ii) Calculate the molar of urea solution if it exerts an osmotic pressure of 2.45 atmosphere at 300K. (R = 0.0821 L atm. mol^(-1) K^(-1) ).

    Van't Hoff equation for osmotic pressure of dilute solution is given as ____.

    A solution with osmotic pressure pi_(1) is separated from another solution of osmotic pressure pi_(2) by SPM solvent flows from pi_(1) to pi_(2) , then

    Assertion : Out of various colligative properties, only osmotic pressure is used to determine the molecular masses of polymers. Reason : Ploymer solutions donot possiss a contant boiling point of freezing point.

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