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A target element A is bombarded with ele...

A target element A is bombarded with electrons and the wavelengths of the characterstic spectrum are measured. A second characteristic spectrum is also obtained , because of an impurity in the target. The wavelengths of the `K_(alpha)` lines are 196 pm (element A) and 169 pm (impurity). If the atomic number of impurity is `z=(10lambda-1)` . Find the value of `lambda` . (atomic number of element A is 27).

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To solve the problem, we will use Moseley's Law, which states that the wavelength of the characteristic X-ray spectrum is inversely proportional to the square of the atomic number of the element. ### Step-by-Step Solution: 1. **Understand the Given Data**: - Wavelength of K-alpha line for element A, \( \lambda_1 = 196 \) pm. - Wavelength of K-alpha line for impurity, \( \lambda_2 = 169 \) pm. - Atomic number of element A, \( Z_A = 27 \). - Atomic number of impurity, \( Z = 10\lambda - 1 \). 2. **Apply Moseley's Law**: According to Moseley's Law: \[ \lambda \propto \frac{1}{(Z - 1)^2} \] This can be expressed in terms of a constant \( k \): \[ \lambda = \frac{k}{(Z - 1)^2} \] 3. **Set Up the Ratio**: For the two elements, we can write: \[ \frac{\lambda_1}{\lambda_2} = \frac{(Z_2 - 1)^2}{(Z_1 - 1)^2} \] Substituting the values: \[ \frac{196}{169} = \frac{(Z - 1)^2}{(27 - 1)^2} \] Simplifying the right side: \[ \frac{196}{169} = \frac{(Z - 1)^2}{26^2} \] 4. **Cross Multiply**: \[ 196 \cdot 26^2 = 169 \cdot (Z - 1)^2 \] 5. **Calculate \( 26^2 \)**: \[ 26^2 = 676 \] Thus, \[ 196 \cdot 676 = 169 \cdot (Z - 1)^2 \] 6. **Calculate \( 196 \cdot 676 \)**: \[ 196 \cdot 676 = 132656 \] So we have: \[ 132656 = 169 \cdot (Z - 1)^2 \] 7. **Divide Both Sides by 169**: \[ (Z - 1)^2 = \frac{132656}{169} \] Calculating the right side: \[ (Z - 1)^2 = 784 \] 8. **Take the Square Root**: \[ Z - 1 = 28 \quad \text{or} \quad Z - 1 = -28 \quad (\text{not valid since } Z \text{ must be positive}) \] Thus, \[ Z = 28 + 1 = 29 \] 9. **Relate \( Z \) to \( \lambda \)**: We know: \[ Z = 10\lambda - 1 \] Therefore: \[ 29 = 10\lambda - 1 \] Solving for \( \lambda \): \[ 10\lambda = 30 \quad \Rightarrow \quad \lambda = 3 \] ### Final Answer: The value of \( \lambda \) is \( 3 \).
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