Home
Class 11
CHEMISTRY
(CH(3))(3)-C-MgCl on reaction with D(2)O...

`(CH_(3))_(3)-C-MgCl` on reaction with `D_(2)O` produces

A

`(CH_(3))_(3)CD`

B

`(CH_(3))_(3)COD`

C

`(CH_(3))_(3)CH`

D

`(CD_(3))_(3)COD`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of `(CH₃)₃C-MgCl` with `D₂O`, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Grignard Reagent**: The compound `(CH₃)₃C-MgCl` is a Grignard reagent where `(CH₃)₃C` (tert-butyl group) is the organic part, and `MgCl` is the magnesium halide. **Hint**: Recognize that Grignard reagents are typically of the form R-MgX, where R is an alkyl or aryl group and X is a halogen. 2. **Understand the Reaction with Water**: Grignard reagents react with water (or in this case, heavy water `D₂O`) to produce hydrocarbons and magnesium hydroxide halides. The general reaction is: \[ R-MgX + H₂O \rightarrow R-H + Mg(OH)X \] Here, `R` represents the alkyl group. **Hint**: Remember that Grignard reagents are highly reactive and will react with any source of protons. 3. **Substituting Heavy Water**: When we use `D₂O` instead of regular water, the hydrogen (H) in the product will be replaced by deuterium (D). Thus, the reaction can be represented as: \[ (CH₃)₃C-MgCl + D₂O \rightarrow (CH₃)₃C-D + Mg(OH)Cl \] **Hint**: Keep in mind that deuterium is an isotope of hydrogen and will replace hydrogen in the product. 4. **Final Product**: The final product of the reaction will be `(CH₃)₃C-D` (tert-butyl deuteride) along with magnesium hydroxide chloride as a byproduct. **Hint**: Always check the stoichiometry of the reaction to ensure all reactants and products are accounted for. ### Conclusion: The reaction of `(CH₃)₃C-MgCl` with `D₂O` produces `(CH₃)₃C-D` and `Mg(OH)Cl`.

To solve the question regarding the reaction of `(CH₃)₃C-MgCl` with `D₂O`, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Grignard Reagent**: The compound `(CH₃)₃C-MgCl` is a Grignard reagent where `(CH₃)₃C` (tert-butyl group) is the organic part, and `MgCl` is the magnesium halide. **Hint**: Recognize that Grignard reagents are typically of the form R-MgX, where R is an alkyl or aryl group and X is a halogen. ...
Promotional Banner

Topper's Solved these Questions

Similar Questions

Explore conceptually related problems

(CH_(3))_(3)CMgBr on reaction with D_(2)O produces :

Me_3 C-MgCl on reaction with D_2 O produces :

(CH_3)_3CMgCl on reaction with D_2O produces

Identify the total number of following compounds which liberate CH_(4) gas on reaction with CH_(3)MgCl (i) H_(2)O (ii) CH_(2)=CH_(2) (iii) Me-C-=C-H

Which S_(N)1 reaction would you expect to take place more rapidly ? (a) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH+HCl Or (ii) (CH_(3))_(3)C Br+H_(2)O to (CH_(3))_(3)COH+HBr (b) (i) (CH_(3))_(3)C Cl+H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) C_(5)H_(5)Cl+H_(2)O to C_(5)H_(5)OH + HCl (c) (i) (CH_(3))_(3)C Cl+ H_(2)O to (CH_(3))_(3)COH + HCl Or (ii) (CH_(3))_(3)C Cl+ CH_(3)OH to (CH_(3))_(3)COCH_(3)+ HCl (d) (i) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(1.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-) Or (ii) (CH_(3))_(3)C Cl(1.0M)+CH_(3)CH_(2)O^(-)(2.0M) overset(C_(2)H_(2)OH)to (CH_(3))_(3)COCH_(2)CH_(3)+Cl^(-)

NARAYNA-ALKANES-level-3
  1. underset((A))(CH(3)-underset(Br)underset(|)overset(CH(3))overset(|)(C)...

    Text Solution

    |

  2. Xoverset(NaOH+CaO)toCH(3)-underset(CH(3))underset(|)overset(CH(3))over...

    Text Solution

    |

  3. CH(2)=CH(2)+H(2)overset(pt,T(1)K)toC(2)H(6) CH(2)=CH(2)+H(2)overset(...

    Text Solution

    |

  4. 2-Methylbutane on reaction with bromine in the presence of sunlight gi...

    Text Solution

    |

  5. Which of the following is not obtained when propyl chloride and methyl...

    Text Solution

    |

  6. The volume of methane at N.T.P formed from 8.2g of sodium acetate by f...

    Text Solution

    |

  7. Reaction of ROH with R'MgX produces

    Text Solution

    |

  8. In Wurtz reaction, n-hexane is obtained from

    Text Solution

    |

  9. The increasing order of reduction of alkyl halides with zinc and dilut...

    Text Solution

    |

  10. nitroethane ca be obtained from ethane by following

    Text Solution

    |

  11. The following substance reacts with ater to give ethane

    Text Solution

    |

  12. (CH(3))(3)-C-MgCl on reaction with D(2)O produces

    Text Solution

    |

  13. The ratio of products, 1-chloropropane to 2-chloropropane respectively...

    Text Solution

    |

  14. Of the five isomeric hexanes, the isomer which can give two monochlori...

    Text Solution

    |

  15. Alkyl halides react with dialkyl copper reagents to give

    Text Solution

    |

  16. 2.84 g of methyl iodide was completely converted into methyl magnesium...

    Text Solution

    |

  17. Which liberate methane gas on treatment with water?

    Text Solution

    |

  18. As compared to melting poitns of even carbon chaini isomers,t he melti...

    Text Solution

    |

  19. Which statement is incorrect about free radical halogenation of alkane...

    Text Solution

    |

  20. Which statement is correct about photochemical bromination of Butane? ...

    Text Solution

    |