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Amount of oxalic acid present in a solut...

Amount of oxalic acid present in a solution can be determined by its titration with `KMnO_(4)` solution in the presence of `H_(2)SO_(4)`. The titration gives unsatisfactory result when carried out in the presence of HCl because HCl

A

gets oxidised by oxalic acid to chlorine

B

Furnishes `H^(+)` ions in addition to those from oxalic acid

C

reduces permanganate to `Mn^(2+)`

D

oxidises oxalic acid to carbon dioxide and water

Text Solution

Verified by Experts

Titration of oxalic acid by `KMnO_(4)` in the presence of HCI gives unsatisfactory result because HCI is a better reduring agent than oxalic acid and HCI rducess prefe3rably `MnO_(4)^(-)`to `Mn^(2+)`.
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