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For the reaction 2N(2)O(4)iff 4NO(2), g...

For the reaction `2N_(2)O_(4)iff 4NO_(2)`, given that `(-d[N_(2)O_(4)])/(dt)=K " and "(d[NO_(2)])/(dt)=K`, then

A

K=2K

B

K'=K

C

2K'= K

D

None of these

Text Solution

Verified by Experts

The correct Answer is:
A

For this reaction,
`2N_(2)O_(4)iff 4NO_(2)`,
Rate expression `=-(1)/(2)(d[N_(2)O_(4)])/(dt)=(1)/(4)(d[NO_(2)])/(dt)`
`"or "-(d[N_(2)O_(4)])/(dt)=(1)/(2)(d[NO_(2)])/(dt)`
`"or "K=(1)/(2)K'`
`"or "K'=2K`
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For the reaction, N_(2)O_(5) rarr 2NO_(2)+1/2O_(2), Given -(d[N_(2)O_(5)])/(dt)=K_(1)[NO_(2)O_(5)] (d[NO_(2)])/(dt)=K_(2)[N_(2)O_(5)] and (d[O_(2)])/(dt)=K_(3)[N_(2)O_(5)] The relation in between K_(1), K_(2) and K_(3) is:

The rate of reaction. 2N_(2)O_(5) to 4NO_(2) + O_(2) can be written in three ways. (-d[N_(2)O_(5)])/(dt) = k[N_(2)O_(5)] (d[N_(2)O_(5)])/(dt) =( k^(')[N_(2)O_(5)]) (d[O_(2)])/(dt) = (k^(')[N_(2)O_(5)]) The relation between k and k^(') are:

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