Home
Class 12
CHEMISTRY
The half-lives for two samples are 0.1 a...

The half-lives for two samples are 0.1 and 0.8 s whose concentrations are 400 and 50 mol `L^(-1)` respectively. The order of the reaction is

A

0

B

1

C

2

D

3

Text Solution

Verified by Experts

The correct Answer is:
C

The ratio of two half-lives and their concentrations are related as `((t_(1//2))_(1))/((t_(1//2))_(2))=[(a_(2))/(a_(1))]^(n-1)` [Here, n = order]
Therefore, `(0.1)/(0.8)=[(50]/(400)]^(n-1)`
On taking log of both sides
`log .(0.1)/(0.8)=(n-1)log. (50)/(400)`
`1 = n-1implies n=2`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    BITSAT GUIDE|Exercise BITSAT Archives|16 Videos
  • CARBOXYLIC ACID AND DERIVATIVES

    BITSAT GUIDE|Exercise All Questions|34 Videos
  • CHEMICAL THERMODYNAMICS

    BITSAT GUIDE|Exercise BITSAT Archives|15 Videos

Similar Questions

Explore conceptually related problems

The half-life of 2 sample are 0.1 and 0.4 seconds. Their respctive concentration are 200 and 50 respectively. What is the order of the reaction

The half-life time for a reaction at initial concentrations of 0.1 & 0.4 mol L^(-1) are 200 s and 50 s respectively . The order of reaction is

Half-life periods for a reaction at initial concentrations of 0.1M and 0.01 are 5 and 50 minutes respectively. Then the order of reaction is

The half-life for a reaction at initial concentration of 0.5 and 1.0 "mole litre"^(-1) are 200 sec and 100 sec respectively. The order of the reaction is

The half-life periofs of a reaction at initial concentration 0.1 mol L^(-1) and 0.5 mol L^(-1) are 200s and 40 s , respectively. The order of the reaction is

For the chemical decomposition of SO_(2)Cl_(2) , its initial concentration is 0.842 mol L^(-1) and the concentration after two hours is 0.210 mol L^(-1) . What is the average rate of the reaction?

BITSAT GUIDE-CHEMICAL KINETICS-BITSAT Archives
  1. The half-lives for two samples are 0.1 and 0.8 s whose concentrations ...

    Text Solution

    |

  2. Following is the graph between log T(50) and log a (a = initial conce...

    Text Solution

    |

  3. Choose the law that corresponds to data shown for the reaction, A + B ...

    Text Solution

    |

  4. A reaction takes place in three steps. The rate constant are k(1), k(2...

    Text Solution

    |

  5. Consider the following reaction 2N(2)O(5)iff 4NO(2)+O(2). If ra...

    Text Solution

    |

  6. For a given reaction, t(1//2) = 1 //ka. The order of this reaction is

    Text Solution

    |

  7. The time taken for 90% of a first order reaction to be completed is a...

    Text Solution

    |

  8. What is the energy of activation of a reaction is its rate doubles whe...

    Text Solution

    |

  9. The active mass of solid is generally taken as

    Text Solution

    |

  10. Following is the graph between log T(50) and log a (a = initial concen...

    Text Solution

    |

  11. Select the law that corresponds to data shown for the following reacti...

    Text Solution

    |

  12. A reaction takes place in three steps. The rate constant are k(1), k(2...

    Text Solution

    |

  13. Consider the following reaction 2N(2)O(5)iff 4NO(2)+O(2). If ra...

    Text Solution

    |

  14. For a given reaction, t(1//2) = 1 //ka. The order of this reaction is

    Text Solution

    |

  15. The time taken for 90% of a first order reaction to be completed is a...

    Text Solution

    |

  16. What is the energy of activation of a reaction is its rate doubles whe...

    Text Solution

    |

  17. The active mass of solid is generally taken as

    Text Solution

    |