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Consider the following reactants, (I) ...

Consider the following reactants,
(I) `CH_(3)-COCH_(3)overset(A)rarr CH_(3)-CH_(2)-CH_(3)`
(II) `(CH_(3))_(3)CH overset(B)rarr (CH_(3))_(3)COH` brgt Here, A and B respectively are

A

Zn(Hg)/HCl(conc.) and `KMnO_(4)`

B

`KMnO_(4)` and Zn(Hg)/conc.HCl

C

`H_(2)//Ni` and `KMnO_(4)`

D

`CH_(3)OH` and `C_(2)H_(5)OH`

Text Solution

Verified by Experts

The correct Answer is:
A
`CH_(3)COCH_(3)underset(2(H))overset(Zn(Hg)//HCl)rarrCH_(3)CH_(2)CH_(3)+H_(2)O`
`(CH_(3))_(3)CH overset(KMnO_(4))rarr underset(3^(@)"alcohol")((CH_(3))_(3)COH)`
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Knowledge Check

  • The given reaction, I. CH_3 COCH_3 oversetArarr CH_3-CH_2-CH_3 II.(CH_3)_3 CH oversetBrarr (CH_3)_3 COH Here, A and B are respectively

    A
    `Zn(Hg)/HCl(conc. )` and `KMnO_4`
    B
    `KMnO_4` and `Zn(Hg)/conc. HCl`
    C
    `H_2/Nl` and KMnO_4`
    D
    `CH_3OH` and `C_2H_5OH`

  • Consider the following reaction CH_(3)- CONH_(2) overset(I)to CH_(3)-NH_(2) overset(II) to CH_(3)NC

    A
    Reaction I is called Hofmann's amine reaction
    B
    Reaction II is called carbyl amine reaction
    C
    Reaction I and II are Hofmann reactions
    D
    Both 'a' and 'b' are correct statements.

  • CH_(3)CH_(2)C-=CH overset(A)(Leftrightarrow)CH_(3)C-=CH_(3) A and B respectively are:

    A
    alc. KOH and `NaNH_(2)`
    B
    `NaNH_(2)` and alc. KOH
    C
    `NaNH_(2)` and Lindlar's catalyst
    D
    Lindlar's catalyst and `NaNH_(2)`

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