Home
Class 12
CHEMISTRY
The product formed during Hell-Volhard-Z...

The product formed during Hell-Volhard-Zelinsky reaction is

A

`R-underset(X)underset(|)CH-COOH`

B

`R-CH_(2)-COX`

C

`R-underset(X)underset(|)overset(X)overset(|)C-COOH`

D

`R-underset(X)underset(|)CH-CH_(2)-COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product formed during the Hell-Volhard-Zelinsky reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Reaction**: The Hell-Volhard-Zelinsky reaction involves the halogenation of carboxylic acids that have at least one alpha-hydrogen. This reaction typically uses chlorine or bromine in the presence of red phosphorus. 2. **Identifying the Reactants**: The reactants in this reaction are carboxylic acids that contain an alpha-hydrogen. The general structure of a carboxylic acid is R-COOH, where R is a hydrocarbon chain. 3. **Mechanism of the Reaction**: - The alpha-hydrogen (the hydrogen atom on the carbon adjacent to the carboxyl group) is replaced by a halogen atom (Cl or Br). - This halogenation occurs through the formation of an acyl halide intermediate, followed by the substitution of the alpha-hydrogen. 4. **Formation of the Product**: The product of the Hell-Volhard-Zelinsky reaction is an alpha-halo-carboxylic acid. This means that the resulting compound will have a halogen atom (X) at the alpha position of the carboxylic acid. 5. **Conclusion**: Therefore, the product formed during the Hell-Volhard-Zelinsky reaction is an alpha-halo-carboxylic acid, specifically represented as R-COX, where X is the halogen (Cl or Br). ### Final Answer: The product formed during the Hell-Volhard-Zelinsky reaction is **alpha-halo-carboxylic acid**. ---

To determine the product formed during the Hell-Volhard-Zelinsky reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Reaction**: The Hell-Volhard-Zelinsky reaction involves the halogenation of carboxylic acids that have at least one alpha-hydrogen. This reaction typically uses chlorine or bromine in the presence of red phosphorus. 2. **Identifying the Reactants**: The reactants in this reaction are carboxylic acids that contain an alpha-hydrogen. The general structure of a carboxylic acid is R-COOH, where R is a hydrocarbon chain. ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDE AND KETONES

    BITSAT GUIDE|Exercise Bitsat Archives|14 Videos
  • CHEMICAL KINETICS

    BITSAT GUIDE|Exercise BITSAT Archives|16 Videos

Similar Questions

Explore conceptually related problems

The Hell-Volhard-Zelinsky reaction is used for preparing

Carboxylic acids having atleast one alpha -hydrogen react with Cl_(2) or Br_(2) in the presence of phosphorus ( or a phosphorus halide) to give alpha -halo acids. This reaction is known as Hell-Volhard-Zelinsky reaction (HVZ reaction), R-CH_(2)COOHunderset(Delta)overset(P//Br_(2))toR-overset(Br)overset(|)"CH"-COOH The HVZ reaction is limited to the formation of alpha -chloro and a-bromo acids and it is sometimes awkward to carry out. The reagents ( X_(2) and P) are noxious and the reaction time is often long and the conditions of reaction are harsh. CH_(3)COOHoverset(Br_(2)//Red P)to(A)overset(NaCN)to(B)overset(HOH//H^(+))to(C ) The product (C) will be:

Carboxylic acids having atleast one alpha -hydrogen react with Cl_(2) or Br_(2) in the presence of phosphorus ( or a phosphorus halide) to give alpha -halo acids. This reaction is known as Hell-Volhard-Zelinsky reaction (HVZ reaction), R-CH_(2)COOHunderset(Delta)overset(P//Br_(2))toR-overset(Br)overset(|)"CH"-COOH The HVZ reaction is limited to the formation of alpha -chloro and a-bromo acids and it is sometimes awkward to carry out. The reagents ( X_(2) and P) are noxious and the reaction time is often long and the conditions of reaction are harsh. CH_(3)CH_(2)COOHoverset(Red P +Br_(2))to(A)overset(alc. KOH)(B) . The product (B) is :

Which of the following undergoes Hell - Volhard - Zelinsky reaction ?

The product formed during the Kolbe's reaction is

Write the reactions involved in the following: (i) Hell-Volhard Zelinsky reaction (ii) Decarboxylation reaction

BITSAT GUIDE-CARBOXYLIC ACID AND DERIVATIVES-All Questions
  1. When salicylic acid is heated with acetic anhydride, we get

    Text Solution

    |

  2. The general formula of the compound obtained as a result of reaction b...

    Text Solution

    |

  3. Pyruvic acid as

    Text Solution

    |

  4. The product of which of the following reaction is capable of changing ...

    Text Solution

    |

  5. The compound that undergoes decarboxylation most readily under mild co...

    Text Solution

    |

  6. The acids, HCOOH and CH(3)COOH are distinguished by

    Text Solution

    |

  7. The reaction given below is called CH(3)CH(2)CH(2)COOHoverset"Red" P...

    Text Solution

    |

  8. The product formed during Hell-Volhard-Zelinsky reaction is

    Text Solution

    |

  9. In the given reactions: Identify X and Y for the above reaction,

    Text Solution

    |

  10. Complete the following reaction

    Text Solution

    |

  11. In a set of the given reactions, acetic acid yields a product C. CH(...

    Text Solution

    |

  12. Complete the synthesis by giving the missing product.

    Text Solution

    |

  13. Role of 2,4-dichlorophenoxy acetic acid is used as

    Text Solution

    |

  14. Acetic acid on warming with hydrazoic acid in presence of conc. H(2)SO...

    Text Solution

    |

  15. Which of the following on heating does not form an anhydride?

    Text Solution

    |

  16. Acetic acid reacts separately with the following alcohols. The rate of...

    Text Solution

    |

  17. Identify A and B in the following reaction CH(3)-CH(3)overset(B)rarr...

    Text Solution

    |

  18. In aqueous solution amino acids moslty exit as

    Text Solution

    |

  19. On heating with oxalic acid at 110^(@)C glycerine gives

    Text Solution

    |

  20. Glycerol is oxidised by bismuth nitrate to produce

    Text Solution

    |