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Statement -1 : Hydrolysis of NCl(3) giv...

Statement -1 : Hydrolysis of `NCl_(3)` gives `NH_(4)OH` and `HOCl` while `PCl_(3)` on hydrolysis gives `H_(3)PO_(3)` and HCl.
Statement -2 : The difference is due to the change in polarity of `P^(+sigma)-CI^(-sigma)` bond in `PCI_(3)` in contrast to `N^(-sigma)-CI^(+sigma)` bond in `NCI_(3)`.

A

Both A and R are correct and R is the correct explanation of A

B

Both A and R are correct and R is not the correct explanation of A

C

A is correct R is wrong

D

A is wrong R is correct

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The correct Answer is:
A
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Statement -1 : Hydrogen of NCl_(3) gives NH_(4)OH and HOCl while PCl_(3) on hydrolysis gives H_(3)PO_(3) and HCl. Statement -2 : The difference is due to the change in polarity of P^(+sigma)-CI^(-sigma) bond in PCI_(3) in contrast to N^(-sigma)-CI^(+sigma) bond in NCI_(3) .

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NARAYNA-15TH GROUP ELEMENTS-Level-VI
  1. Assertion: PCI(5) in aqueous medium is a better oxidant than NCl(3) ...

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  2. Assertion: In hydrazoic acid oxidation state of nitrogen is -(1)/(3) ...

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  3. Statement -1 : Hydrolysis of NCl(3) gives NH(4)OH and HOCl while PCl(...

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  4. Real gases show deviation from ideal behaviour at low temperature and ...

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  5. Assertion Bond angles of NH(3),PH(3),AsH(3) and SbH(3) decrease in ord...

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  6. Trisilyamine (SiH(3))(3) N is

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  7. Orthophosphoric acid is

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  8. Assertion (A) : Stability of NH(3) is greater than PH(3) Reason (R) ...

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  9. Which of the following oxide/oxy-anions does not contain P-O-P linkage...

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  10. Assertion: Nitric oxide is paramagnetic in the liquid and solid states...

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  11. Conc. HNO(3) can be stored in a container made of

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  12. Assertion: Red phophorus is less volatile then white phosphorus. Rea...

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  13. Assertion : white phosphorus is more reactive than red phosphorus Re...

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  14. Which of the following compounds does not liberate nitrogen gas on tre...

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  15. The true statement among the following are:

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  16. The IUPAC name of the element with atomic number Z = 109 is

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  17. Valency and oxidation number of nitrogen in N(2)O(5)

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  18. Complete the following. HNO(3)+P(4)O(10)to

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  19. The number of hydroxyl group in pyrophosphoric acid is

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  20. Find the number of ppi-ppi bonds in N(2)O.

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