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Trisilyamine (SiH(3))(3) N is...

Trisilyamine `(SiH_(3))_(3)` N is

A

Both A and R are correct and R is the correct explanation of A

B

Both A and R are correct and R is not the correct explanation of A

C

A is correct R is wrong

D

A is wrong R is correct

Text Solution

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The correct Answer is:
B
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In trimethylamine, the nitrogen has a pyramidal geometry whereas in trisilylamine N(SiH_(3)) _(3), it has a planar geometry. What is the reaons behind this ?

The length of the N - Si bond in (SiH_(3))_(3) N is shorter than what is normally expected for an N - Si single bond. This is due to

Assertion In case of (CH_(3))_(3)N geometry is pyramidal but in case of (SiH_(3))_(3)N it is planar Reasoning The maximum covalency of Si is six but that of C is four .

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The geometry with respect ot the central atom of the following molecules are N(SiH_(3))_(3), Me_(3)N , (SiH_(3))_(3) P

NARAYNA-15TH GROUP ELEMENTS-Level-VI
  1. Real gases show deviation from ideal behaviour at low temperature and ...

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  2. Assertion Bond angles of NH(3),PH(3),AsH(3) and SbH(3) decrease in ord...

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  3. Trisilyamine (SiH(3))(3) N is

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  4. Orthophosphoric acid is

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  5. Assertion (A) : Stability of NH(3) is greater than PH(3) Reason (R) ...

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  6. Which of the following oxide/oxy-anions does not contain P-O-P linkage...

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  7. Assertion: Nitric oxide is paramagnetic in the liquid and solid states...

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  8. Conc. HNO(3) can be stored in a container made of

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  9. Assertion: Red phophorus is less volatile then white phosphorus. Rea...

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  10. Assertion : white phosphorus is more reactive than red phosphorus Re...

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  11. Which of the following compounds does not liberate nitrogen gas on tre...

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  12. The true statement among the following are:

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  13. The IUPAC name of the element with atomic number Z = 109 is

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  14. Valency and oxidation number of nitrogen in N(2)O(5)

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  15. Complete the following. HNO(3)+P(4)O(10)to

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  16. The number of hydroxyl group in pyrophosphoric acid is

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  17. Find the number of ppi-ppi bonds in N(2)O.

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  18. VA group elements form tri oxides and pentoxides of the type M(2)O(3) ...

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  19. The correct order of the oxidation states of nitrogen in NO, N(2)O, N...

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  20. Let us consider the following reactions: NH(3)+NaOCI overset("indilu...

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