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A white 'A' on heating decomposes to pro...

A white 'A' on heating decomposes to produce two products 'B' and 'C'. 'B' on reaction with white phosphorous produces 'D', which is a strong dehydrating agent. 'D' on reaction with perchloric acid converts it to its anhydride.
The compound 'A' is:

A

`NH_(4)NO_(3)`

B

`NH_(4)NO_(2)`

C

`(NH_(4))_(2)Cr_(2)O_(7)`

D

`NH_(4)CIO_(4)`

Text Solution

Verified by Experts

The correct Answer is:
A
`NH_(4)NO_(3) overset(Delta)(rarr)N_(2)O+H_(2)O`
`N_(2)O+P_(4)rarrP_(4)O_(10)+N_(2)`
`HClO_(4)+P_(4)O_(10)rarrCl_(2)O_(7)+HPO_(3)`
`A=NH_(4)NO_(3),C=H_(2)O,D=P_(4)O_(10)`
`P_(4)O_(10)+6H_(2)Orarr4H_(3)PO_(4)`.
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NARAYNA-15TH GROUP ELEMENTS-Level-VI
  1. An oxyacid of phosphorous has the following properties: Complete neutr...

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  2. An oxyacid of phosphorous has the following properties: Complete neutr...

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  3. A white 'A' on heating decomposes to produce two products 'B' and 'C'....

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  4. A white 'A' on heating decomposes to produce two products 'B' and 'C'....

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  5. A white 'A' on heating decomposes to produce two products 'B' and 'C'....

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  6. B is:

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  7. C is:

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  8. D is:

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  9. Nitrogen forms the largest number of oxides as it is capable of formin...

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  10. Nitrogen forms the largest number of oxides as it is capable of formin...

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  11. Nitrogen forms the largest number of oxides as it is capable of formin...

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  12. H(3)PO(4) overset(Delta)rarr X overset(Delta)rarrY gives a white preci...

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  13. H(3)PO(4) overset(Delta)rarr X overset(Delta)rarrY gives a white preci...

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  14. H(3)PO(4) overset(Delta)rarr X overset(Delta)rarrY gives a white preci...

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  15. NH(3)+O(2)overset("Pt")to(A) (A)+O(2)to (B)(brown fumes) (B)+H(2)o...

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  16. NH(3)+O(2)overset("Pt")to(A) (A)+O(2)to (B)(brown fumes) (B)+H(2)o...

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  17. NH(3)+O(2)overset("Pt")to(A) (A)+O(2)to (B)(brown fumes) (B)+H(2)o...

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  18. Action of concentrated nitric acid (HNO(3)) on metallic tin produces

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  19. Which fo the following metal is rendered passive by the action of high...

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  20. Action of concentrated nitric acid (HNO(3)) on metallic tin produces

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