Electrolysis is an important technique for extraction of metals, and each ion of the solution needs a minimum voltage to get discharged and this value is expressed in terms of discharge potential. For some metal ions the discharge potentials follow the order given below : `Li^(+) gt K^(+) gt Ca^(2+) gt Na^(+) gt Mg^(2+) gt Al^(3+) gt Zn^(2+) gt Fe^(2+) gt Ni^(2+) gt H_(3)O^(+) gt Cu^(2+) gt Hg_(2)^(2+) gt Ag^(+) gt Au^(3+)` For some anions the discharge potentials are in the order : `SO_(4)^(2-) gt NO_(3)^(-) gt OH^(-) gt Br^(-) gt I^(-)` When aqueous solution of cupric bromide is electrolyzed the product obtained at cathode will be :
A
Cu
B
`H_(2)`
C
`Br_(2)`
D
`O_(2)`
Text Solution
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The correct Answer is:
d
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Electrolysis is an important technique for extraction of metals, and each ion of the solution needs a minimum voltage to get discharged and this value is expressed in terms of discharge potential. For some metal ions the discharge potentials follow the order given below : Li^(+) gt K^(+) gt Ca^(2+) gt Na^(+) gt Mg^(2+) gt Al^(3+) gt Zn^(2+) gt Fe^(2+) gt Ni^(2+) gt H_(3)O^(+) gt Cu^(2+) gt Hg_(2)^(2+) gt Ag^(+) gt Au^(3+) For some anions the discharge potentials are in the order : SO_(4)^(2-) gt NO_(3)^(-) gt OH^(-) gt Br^(-) gt I^(-) The product formed at anode and cathode, when dilute H_(2)SO_(4) is electrolysed are :
Electrolysis is an important technique for extraction of metals, and each ion of the solution needs a minimum voltage to get discharged and this value is expressed in terms of discharge potential. For some metal ions the discharge potentials follow the order given below : Li^(+) gt K^(+) gt Ca^(2+) gt Na^(+) gt Mg^(2+) gt Al^(3+) gt Zn^(2+) gt Fe^(2+) gt Ni^(2+) gt H_(3)O^(+) gt Cu^(2+) gt Hg_(2)^(2+) gt Ag^(+) gt Au^(3+) For some anions the discharge potentials are in the order : SO_(4)^(2-) gt NO_(3)^(-) gt OH^(-) gt Br^(-) gt I^(-) When conc. H_(2)SO_(4) is electrolysed with high current using Pt electrodes, the product obtained at anode is :
Electrolysis is an important technique for extraction of metals, and each ion of the solution needs a minimum voltage to get discharged and this value is expressed in terms of discharge potential. For some metal ions the discharge potentials follow the order given below : Li^(+) gt K^(+) gt Ca^(2+) gt Na^(+) gt Mg^(2+) gt Al^(3+) gt Zn^(2+) gt Fe^(2+) gt Ni^(2+) gt H_(3)O^(+) gt Cu^(2+) gt Hg_(2)^(2+) gt Ag^(+) gt Au^(3+) For some anions the discharge potentials are in the order : SO_(4)^(2-) gt NO_(3)^(-) gt OH^(-) gt Br^(-) gt I^(-) A mixture containing chlorides of sodium, calcium and zinc is electrolysed in presence f wate. The product obtained at cathode will be :