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Consider the following compounds Am...

Consider the following compounds

Among the compounds A and B, the vapour pressure of B at a particular temperature is

A

higher than that of A

B

lower than that of A

C

same as that of A

D

None of the above

Text Solution

Verified by Experts

The correct Answer is:
A

In o-nitrophenol, Intramolecular H-bonding is present between `-OH` and `-NO_(2)` groups, whereas p-nitrophenol forms intermolecular H-bonding. Thus, vapour pressure of B is higher than that of A.
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