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What will be the product of the followin...

What will be the product of the following reaction ?
`{:(" "CH_(3)),(" |"),(H_(3)C-C-Br+Na-O-CH_(3)rarr),(" |"),(" "CH_(3)):}`

A

`{:(CH_(3)-C=CH_(2)),(" |"),(" "CH_(3)):}`

B

`{:(" "CH_(3)),(" |"),(CH_(3)-O-C-CH_(3)),(" |"),(" "CH_(3)):}`

C

`CH_(3)-CH_(2)-CH_(2)-CH_(3)`

D

`{:(CH_(3)-CH-CH_(3)),(" |"),(" "CH_(3)):}`

Text Solution

Verified by Experts

The correct Answer is:
A
When tertiary alkyl halide is treated with sodium alkoxide then elimination reaction completes over substitution reaction because alkoxides are not only nucleophiles but strong base as well. Therefore, alkenes are formed instead of ethers.
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Knowledge Check

  • What will be the product of the reaction ? H_(3)C-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-Br+Na-O-CH_(3) rarr

    A
    `CH_(3)-underset(CH_(3))underset(|)(C)=CH_(2)`
    B
    `CH_(3)-O-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH_(3)`
    C
    `CH_(3)-CH_(2)-CH_(2)-CH_(3)`
    D
    `CH_(3)-underset(CH_(3))underset(|)(CH)-CH_(3)`

  • What is the major product of the following reaction ? CH_(3)CH_(2)- overset(O)overset("||")C-H+CH_(3)MgBr overset(H_(2)O //H^(+))rarr

    A
    1-Butanol
    B
    Butanal
    C
    2-Butanol
    D
    Butanone

  • Identify the exculsive product of the following reaction (CH_(3))_(3)C CH(CH_(3))OHoverset(Conc.HCl)(rarr)

    A
    `(CH_(3))_(3)C CH=CH_(2)`
    B
    `(CH_(3))_(3)C ClCH(CH_(3))_(2)`
    C
    `(CH_(3))_(3)C CH(CH_(3))Cl`
    D
    `(CH_(3))_(2)C=C(CH_(3))_(2)`

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