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In the presence of acid, the initial con...

In the presence of acid, the initial concentration of cane sugar was reduced from 0.2 M to 0.1 M in 5 h and to 0.05 M in 10 h. The reaction must be of

A

zero order

B

first order

C

second order

D

fractional order

Text Solution

Verified by Experts

The correct Answer is:
B

For the first order reaction
Rate `prop[A] implies ([A])/("Rate")="Constant"(k)`
(i) When `Deltax=0.2-0.1=0.1, Deltat=5h,[A]=0.2`
Hence, `(0.2)/(0.1//5)=10=k`
(ii) When `Deltax=0.1-0.05=0.05,Deltat=5h,[A]=0.1`
Hence, `(0.1)/(0.05//5)=10=k`
Hence, reaction follows first order rate law.
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