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IUPAC name of [Pt(NH(3))(2)Cl(NO(2))] is...

IUPAC name of `[Pt(NH_(3))_(2)Cl(NO_(2))]` is

A

platinum diaminechloronitrite

B

Chloronitrito-N-ammeniplatinum (II)

C

diammenichloridonitrito-N-plantinum(II)

D

diamminechloronitrito-N-plantinate(II)

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The correct Answer is:
To determine the IUPAC name of the coordination complex `[Pt(NH₃)₂Cl(NO₂)]`, we can follow these steps: ### Step 1: Identify the Ligands The ligands present in the complex are: - Ammonia (NH₃), which is a neutral ligand. - Chloride (Cl), which is a negatively charged ligand. - Nitrite (NO₂), which is also a negatively charged ligand. ### Step 2: Name the Ligands in Alphabetical Order When naming the ligands, we list them in alphabetical order based on their names: - Amine (from NH₃) is called "ammine." - Chloride (from Cl) is called "chlorido." - Nitrite (from NO₂) is called "nitrito." Since there are two ammonia ligands, we use the prefix "di-" to indicate this. Thus, the ligands in alphabetical order are: 1. Ammine (diammine for two NH₃) 2. Chlorido 3. Nitrito ### Step 3: Identify the Coordination Number and Linkage The nitrite ligand (NO₂) can bind through nitrogen or oxygen, but in this case, it is specified to bind through nitrogen, so we will denote it as "nitrito-N." ### Step 4: Name the Metal and Its Oxidation State The metal in the complex is platinum (Pt). To determine the oxidation state of platinum, we consider the charges of the ligands: - Ammonia (NH₃) is neutral (0 charge). - Chloride (Cl) has a charge of -1. - Nitrite (NO₂) has a charge of -1. The total charge contributed by the ligands is -2. To balance this, platinum must have an oxidation state of +2. ### Step 5: Combine All Parts to Form the IUPAC Name Now we can combine all the parts: - Ligands: diammine, chlorido, nitrito-N - Metal: platinum - Oxidation state: (II) Putting it all together, the IUPAC name of the complex is: **Diamminedichloridonitrito-N-platinum(II)** ### Final Answer **Diamminedichloridonitrito-N-platinum(II)** ---

To determine the IUPAC name of the coordination complex `[Pt(NH₃)₂Cl(NO₂)]`, we can follow these steps: ### Step 1: Identify the Ligands The ligands present in the complex are: - Ammonia (NH₃), which is a neutral ligand. - Chloride (Cl), which is a negatively charged ligand. - Nitrite (NO₂), which is also a negatively charged ligand. ...
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NARAYNA-COORDINATION COMPLEXES-LEVEL - IV
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  4. Which of the following is most stable?

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  5. Which of the following complex formed by Cu^(2+) ions is most stable?

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  7. Indicate the complex ion which shows geometrical isomerism.

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  8. When 1 mol CrCl(3).6H(2)O is treated with excess of AgNO(3), 3 mol of ...

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  9. When 0.1 mol CoCl(3)(NH(3))(5) is treated with excess of AgNO(3), 0.2 ...

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  10. The correct IUPAC name of [Ot(NH(3))(2)Cl(2)] is

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  11. The stabilization of coordination compound due to chelation is called ...

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  12. The CFSE for octahedral [CoCl(6)]^(4-) is 18,000 cm^(-1). The CFSE for...

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  13. Due to the presence of ambidenate ligands coordination compounds show ...

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  14. The compounds [Co(SO(4))(NH(3))(5)]Br and [Co(SO(4))(NH(3))(5)]Cl

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  15. Which of the following is not chelating agent (a) Thiosulphate (b)...

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  16. Which of the following species is not expected to be a ligand?

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  17. What kind of isomerism exists between [Cr(H(2)O)(6)]Cl(3) (violet) and...

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  18. IUPAC name of [Pt(NH(3))(2)Cl(NO(2))] is

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  19. On the basis of the following observations made with acqueous solution...

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  20. Calculate the overall complex dissociation equilibrium constant for th...

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