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STATEMENT-1 The value of Delta(o) for M^...

STATEMENT-1 The value of `Delta_(o)` for `M^(3+)` complexes are always much higher than value for `M^(2+)` complexes
STATEMENT-2 : The crystal field stabilization energy of `[Co(NH_(3))_(6)]^(3+) lt [Rh(NH_(3))_(6)]^(3+)`

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for statement-1.

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explation for statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

Verified by Experts

(B) , `Delta_(0)` increase as charge and nuclear charge i.e. the value of n of cation increase
`Delta_(0)` for `[Co(NH_(3))_(6)]^(3+)=296 KJ "mol"^(-1)`
`[Rh(NH_(3))_(6)]^(3+)=406 KJ "mol"^(-1)`
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The crystal field stabilisation energy of [Co(NH_(3))_(6)]Cl_(3) is:

Statement-1: The value of Delta_(0) for M^(3+) complexes are always much higher than value for M^(2+) complexes (for the same set of ligands) Statement-2: The crystal field stabilization energy of [Co(NH_(3))_(6)]^(3+)lt[Rh(NH_(3))_(6)]^(3+) .

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