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The following complexs are given? tran...

The following complexs are given?
trans-`[Co(NH_(3))_(4)1_(2)]^(o+)`
`cis-[Co(NH_(3))_(2)(en)_(2)]^(3+)`
trans-`[Co(NH_(3))_(2)(en)_(2)]^(3+)`
`[NiI_(4)]^(2-)`
`[TiF_(6)]^(2-)`
`[CoF_(6)]^(3-)`
Choose the correct code .

A

(1),(2) are optically active,

B

(2) is optically active, (1), (3) are optically inactive

C

(4),(6) are colourless (5) is coloured

D

(4) is coloured and (5) is colourless

Text Solution

Verified by Experts

The correct Answer is:
b,d

(1) and (3) are symmetrical not opticaly active. (5) has `Ti^(4+)(d^(0))` configuration.
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The following complexs are given? trans- [Co(NH_(3))_(4)1_(2)]^(o+) cis-[Co(NH_(3))_(2)(en)_(2)]^(3+) trans- [Co(NH_(3))_(2)(en)_(2)]^(3+) [Ni1_(4)]^(2-) [Tif_(6)]^(2-) [CoF_(6)]^(3-) Choose the correct code .

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Draw cis nd trans isomers of [Co(NH_(3))_(4)Cl_(2)]^(+) ion.

Which of the following compounds show optical isomerism? I. cis -[Co(NH_(3))_(4) Cl_(2)]^(+) II. Trans - [Co(en)_(2) Cl_(2)]^(+) III. Cis - [Co(en)_(2) cl_(2)]^(+) IV. [Co(en)_(3)]^(3+) Choose the correct answer form the codes given below.

Which of the following is more stable ? (1) K_(4)[Fe(CN)_(6)] or K_(3)[Fe(CN)_(6)] (2) [Co(NH_(3))_(6)]^(3+) or [Co(en)_(2)(NH_(3))_(2)]^(3+) (3) [NiCl_(4)]^(2-) or [Ni(CN)_(4)]^(2-)

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NARAYNA-COORDINATION COMPLEXES-Multiple Answer Questions
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  2. Which of the following are cis isomers ?

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  3. The following complexs are given? trans-[Co(NH(3))(4)1(2)]^(o+) ci...

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  4. Among the following which is most stable? Choose the correct code

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  5. Which of the following is/are correct?

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  6. The magnitude of crystal field stabilization energy depends on

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  7. Complex ions [NiCl(4)]^(2-),[Ni(CN(4)]^(2-) Similar in theior given ...

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  8. Select correct statement(s) regarding given complexes:

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  9. Complex compound [Co(SCN)(2)(NH(3))(4)]Cl exhibits:

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  10. Which of the following compound has/have effective atomic number equal...

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  11. K(2)[Ni(CN)(4)] underset(NH(3))overset("K in liq.")to"X' Regarding t...

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  12. Which one of the following statement(s) is/are false?

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  13. Which of the following is correct about Tetraamminedithiocyanato-s cob...

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  14. Select the correct statement

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  15. Which of the following obey18e^(-)rule?

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  16. Which of the following obey EAN rule?

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  17. Which of the following are four coordinated cpomplexes?

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  18. In Ni^(2+) octahedral complex ,which of the following ligands do not p...

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  19. Explain the following : (i) Low spin octahedral complexes of nicke...

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  20. which of the following exhibits optical activity?

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