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The Lassaigne's extract is boiled with d...

The Lassaigne's extract is boiled with dil. `HNO_(3)` before testing for halogens because

A

Silver halides are solube in `HNO_(3)`

B

`Na_(2)S` and `NaCN` are decomposed by `HNO_(3)`

C

`Ag_(2)S` is soluble is `HNO_(3)`

D

`AgCN` is soluble is `HNO_(3)`

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The correct Answer is:
B

`HNO_(3)` is added to decopose `Na_(2)S` and `NaCN` otherwise `Na_(2)S` will gie blacke pot. Of `Ag_(2)S` and `NaCN` will white ppt. of `AgCN` which would interference the test of halogens.
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NARAYNA-PRACTICAL ORGANIC CHEMISTRY-SCQ_TYPE
  1. Lassaigne's test for the detection of nitrogen fails in

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  2. The compound that does not give a blue colour in Lassaigne's test is

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  3. The Lassaigne's extract is boiled with dil. HNO(3) before testing for ...

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  4. In Carius tube the compound ClCH(2)-COOH was heated with fuming HNO...

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  5. If 0.24 g of a volatile liquid upon vaporization gives 45 ml of vapour...

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  6. In sodium fusion test of roganilc compound, the nitrogen of a organic ...

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  7. Which of the following will give blood red colour with FeCl(5) in sodi...

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  8. Sulphide ions react with Na(2) [Fe(NO)(CN)(5)] to form a purple colour...

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  9. Which of the following will not give test for N in sodium extract?

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  10. Which of the following compounds, when heated with HNO(3) (conc), cool...

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  11. A substance was known by its mode of synthesis to contain 10 atoms of ...

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  12. Compound A,C(7)H(8)O, is insoluble in water, dilute HCl, and aquenous ...

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  13. Compounds I and II can be distinguished by using reagent. (I) -4-Ami...

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  14. A set of reagents (1 to 8) are successively rected with the following ...

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  15. Which one of the following will not give white precipitate with ammoni...

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  16. Which of the following alcohols will show positive iodoforms test?

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  17. The compound A gives following reactions. It structure can be

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  18. In compound A(C(30)H(60)O) following tests are observed negatively. A ...

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  19. A mixture of two organic compound gives red coloured precipitate with ...

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  20. Give the correct order of initials T or F for following statements. Us...

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