Home
Class 12
CHEMISTRY
The most stable conformation of 2, 3- di...

The most stable conformation of 2, 3- dimethyl butane is

A

B

C

D

Nono of these

Text Solution

AI Generated Solution

The correct Answer is:
To determine the most stable conformation of 2,3-dimethylbutane, we need to analyze the different conformations that this molecule can adopt. Here’s a step-by-step solution: ### Step 1: Understand the Structure of 2,3-Dimethylbutane 2,3-Dimethylbutane is a branched alkane with the following structure: - It has a butane backbone (4 carbon atoms). - There are two methyl groups (−CH₃) attached to the second and third carbon atoms of the butane chain. ### Step 2: Identify Possible Conformations Alkanes can adopt various conformations due to the rotation around the carbon-carbon single bonds. The main types of conformations are: - Staggered conformation: where the atoms are positioned at maximum distance from each other. - Eclipsed conformation: where the atoms are positioned directly in front of each other, leading to increased steric hindrance and torsional strain. ### Step 3: Analyze Staggered Conformations In the staggered conformation, the methyl groups can be positioned in different orientations: - **Anti conformation**: The two methyl groups are opposite each other (180° apart). - **Gauche conformation**: The two methyl groups are adjacent (60° apart). ### Step 4: Evaluate Stability The stability of a conformation is influenced by steric hindrance and torsional strain: - **Eclipsed conformations** are less stable due to increased steric repulsion between the groups. - **Staggered conformations** are more stable, with the anti conformation being the most stable due to minimal steric hindrance. ### Step 5: Determine the Most Stable Conformation For 2,3-dimethylbutane: - The **anti conformation** is the most stable because the two bulky methyl groups are positioned opposite each other, minimizing repulsion. - The **gauche conformation** is less stable than the anti conformation due to closer proximity of the methyl groups, which increases steric hindrance. ### Conclusion The most stable conformation of 2,3-dimethylbutane is the **anti conformation** where the two methyl groups are positioned 180° apart from each other. ---
Promotional Banner

Topper's Solved these Questions

  • ISOMERISM

    HIMANSHU PANDEY|Exercise Level 3 (Q.51 To Q.75)|25 Videos
  • ISOMERISM

    HIMANSHU PANDEY|Exercise Level 3 (Q.76 To Q.100)|25 Videos
  • ISOMERISM

    HIMANSHU PANDEY|Exercise Level 3 (Q.1 To Q.25)|25 Videos
  • HALIDES

    HIMANSHU PANDEY|Exercise Subjective Type Problems|10 Videos
  • NOMENCLATURE

    HIMANSHU PANDEY|Exercise Section Iv (Q.26 To Q.26)|1 Videos

Similar Questions

Explore conceptually related problems

The most stable conformation of 2, 3-dibromobutane is -

In the following the most stable conformation of n -butane is:

The most stable conformation of n-butane is

Which is the most stable conformation of 3,4-dimethylihexane?

HIMANSHU PANDEY-ISOMERISM-Level 3 (Q.26 To Q.50)
  1. Which of the following compound is optically active

    Text Solution

    |

  2. Which of the following structures has D- configuration ?

    Text Solution

    |

  3. Which of the following sawhorse projection formulae repersents the gau...

    Text Solution

    |

  4. How many gauche conformations are possible for n- butane ?

    Text Solution

    |

  5. The most stable conformation of cyclohexane is :

    Text Solution

    |

  6. Which of the following cinfromations n- butane has a centre of symmer...

    Text Solution

    |

  7. Which of the following comformations of n- butane has a plane of symme...

    Text Solution

    |

  8. The most stable conformation of 2, 3- dimethyl butane is

    Text Solution

    |

  9. Total number of stereoisomers of the compound CH(3)-CH=CH-underset(...

    Text Solution

    |

  10. Which of the following pairs of structures pepresent conformational is...

    Text Solution

    |

  11. Which of the following structures is chrial

    Text Solution

    |

  12. Which of the followong compounds can be optically active S...

    Text Solution

    |

  13. Which one of the following compounds will show enantomers

    Text Solution

    |

  14. The meso form of 2,3 4- pentanetriol is :

    Text Solution

    |

  15. Which of the following compounds is chrial ?

    Text Solution

    |

  16. Which one following is the most stable conformer ?

    Text Solution

    |

  17. Which one of the following is most stable ?

    Text Solution

    |

  18. Which among the following compounds will show geometrical

    Text Solution

    |

  19. First member of optically active alkene is :

    Text Solution

    |

  20. Consider the following parirs of compounds ? n Which among the foll...

    Text Solution

    |