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Which of the following compounds will gi...

Which of the following compounds will give `S_(N^(1))` reaction?

A

`H_(3)C-CH_(2)-Br`

B

C

`H_3C-overset(..)underset(..)O-CH_2-Cl`

D

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The correct Answer is:
C, D
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Which of the following compounds will not give S_(N^(2)) reaction?

Nucleophilic aliphatic substitution reaction is mainly of two types: S_(N)1 and S_(N)2 . The S_(N)1 mechanism is a two step process. Reaction velocity of S_(N)1 reaction depends only on the concentration of the substrate. Since product formation takes place by the formation of carbocation, optically active substrate gives (+) and (-) forms of the product. In most of the cases the product usually consits of 5-20% inverted product and 80-95% racemised species. The more stable the carbocation, the greater is the proportion of racemisation. In solvolysis reaction, the more nucleophilic the solvent, the greater is the proportion of inversion. Which one of the following compound will give S_(N)1 reaction predominantly?

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HIMANSHU PANDEY-HALIDES-More Than One Correct (Q.1 To Q.25)
  1. Find out correct statements about Grignard reagent :

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  2. R-X+Mgoverset(ether)rarrR-MgXoverset(CH(3)OH)rarr n-butane What can ...

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  3. Point out the following incorrect Grignard synthesis :

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  4. Complete the following reaction

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  5. Which of the following reactions are correct?

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  6. Which of the following compounds give alcohol on reaction with RMgX?

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  7. Which of the following ketone does not react with CH(3)MgBr?

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  8. R-overset(O)overset(||)C-Cl+ZrarrR-overset(O)overset(||)C-R The reag...

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  9. Match the following columns

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  10. Match the following columns

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  11. Choose the correct among the following statements :

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  12. In which product formation takes place according to Hofmann's rule ?

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  13. Consider the following statements and pick up the correct statements :

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  14. Which of the following compounds will give syn-elimination reaction ?

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  15. Which of the following compounds will not give S(N^(2)) reaction?

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  16. Which of the following compounds will give S(N^(1)) reaction?

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  17. Which of the following are correct for the given reaction?

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  18. Which of the following halides undergo E(2) elimination?

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  19. In which of the following cases, the major product has been correctly ...

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  20. Pick the correct orders of reactivity

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