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Cl-overset(O)overset(||)C-OC(2)H(5)overs...

`Cl-overset(O)overset(||)C-OC_(2)H_(5)overset((1)'X'RMgX)underset(NH_(4)Cl)rarr3^(@)` Alcohol. Find out value of 'X'.

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Cl -overset(O) overset(||)C-OC_(2)H_(5)- overset((1)'X'RMgX) underset((2)NH_(4)Cl)to 3^(@)"alcohol"

Complete the following: a. b. c. d. e. f. g. h. PhCHO + Cl_(2) overset("No catalyst")rarr(A) i. j. PhCHO+(C_(2)H_(5)CO)_(2)O overset(C_(2)H_(5)COONa)rarr A k. l. m. n. o. p. q. r. s. PhCOCH_(3)+SeO_(2)rarr (A) t. PhCH=CH-overset(O)overset(||)C-Ph+KCN overset(CH_(3)COOH)rarr (A) u. Ph-underset(CN)underset(|)CH-overset(O)overset(||)C-CH_(3) overset((i)H_(3)O^(o+))underset((ii)Delta)rarr (A) v. w. Ph-overset(OH)overset(|)underset(Ph)underset(|)C-CH_(2)NH_(2) overset(HNO_(2))rarr (A) overset("Oxidation")rarr (B) x. PhCOPh+KOH rarr (A)+(B) y. z.

Knowledge Check

  • Cl-overset(O)overset(||)C-Cloverset(PhMgBr(excess))underset(H_(3)^(oplus)O)rarr(X), Product (X) is :

    A
    `Ph-overset(O)overset(||)C-Cloverset`
    B
    `Ph-overset(O)overset(||)C-Phoverset`
    C
    `Ph-overset(OH)overset(|)underset(Ph)underset(|)C-Phoverset`
    D
    `Ph-overset(O)overset(||)C-O-Ph`

  • Cl-overset(OH)overset(|)C-OEt""overset(PhMgBr(excess))underset(H_(3)^(oplus)O)rarr Product :

    A
    `Ph-overset(OH)overset(|)underset(Ph)underset(|)C-Ph`
    B
    `Ph-overset(O)overset(||)C-Cl`
    C
    `Ph-overset(O)overset(||)C-OEt`
    D
    `Ph-overset(O)overset(||)C-Ph`

  • CH_(3)-CH_(2)-overset(O)overset(||)(C )-OC_(2)H_(5) overset(Naoverset(**)(O)H)underset(H_(2)O^(**))rarr Products of the above reaction contain

    A
    `CH_(3)-CH_(2)-overset(O)overset(||)(C )-overset(**)(O^(-))`
    B
    `CH_(3)-CH_(2)-overset(O^(**))overset(||)(C )-O^(-)`
    C
    `CH_(3)CH_(2)-overset(**)(O)-H`
    D
    Both (a) and (b)

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    RMgXoverset((i)CH_(3)CN)underset(NH_(4)Cl)rarr(A)overset(RMgX)underset(NH_(4)Cl)rarr(B),(B) will be :

    The final product (III) obtained in the reaction sequence. CH_(3) =overset(O)overset(||)(C) -CH_(2)-overset(O)overset(||)C-OC_(2)H_(5) overset((i)Na)underset((ii) C_(6)H_(5)CH_(2)Br)(rarr)I overset(H_(5)O^(+)) (rarr) II overset(heat)underset(-CO_(2))(rarr)III Product I is :-

    CH_(3)MgX underset(H^(+),H_(2)O)overset(CH_(3)-overset(O)overset(||)(C)-OC_(2)H_(5))(rarr)(A)overset(Na)(rarr)(B)overset(C_(2)H_(5)OH)(rarr)(C ),(C ) is :

    C_(2)H_(5)O-overset(O)overset(||)(C )-OC_(2)H_(5) overset(2MeMgBr)(rarr) (A) . The product (A) formed can:

    NH_(2)-overset(O)overset(||)C-NH_(2) underset(Cl_(2))overset(NaOH)rarr Major product is :

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