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CH(3)COCl+C(2)H(5)OH overset("Pyridine")...

`CH_(3)COCl+C_(2)H_(5)OH overset("Pyridine")rarr CH_(3)COOC_(2)H_(5)+HCl`
The function pyridine in the above reaction is:

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To understand the function of pyridine in the given reaction, let's break down the process step by step. ### Step 1: Identify the Reactants The reactants in the reaction are: - Acetyl chloride (CH₃COCl) - Ethyl alcohol (C₂H₅OH) ### Step 2: Understand the Reaction When acetyl chloride reacts with ethyl alcohol, it forms an ester (ethyl acetate, CH₃COOC₂H₅) and hydrochloric acid (HCl) as a byproduct. The reaction can be represented as: \[ \text{CH}_3\text{COCl} + \text{C}_2\text{H}_5\text{OH} \xrightarrow{\text{Pyridine}} \text{CH}_3\text{COOC}_2\text{H}_5 + \text{HCl} \] ### Step 3: Role of Pyridine Pyridine acts as a base in this reaction. Its primary function is to absorb the hydrochloric acid (HCl) that is released during the reaction. ### Step 4: Mechanism of the Reaction 1. **Formation of the Ester**: - The hydroxyl group (-OH) from ethyl alcohol attacks the carbonyl carbon of acetyl chloride, leading to the formation of a tetrahedral intermediate. - This intermediate then collapses, releasing HCl and forming the ester (ethyl acetate). 2. **Absorption of HCl**: - If pyridine is present, it will react with the liberated HCl. Pyridine has a lone pair of electrons on the nitrogen atom, which allows it to accept the proton (H⁺) from HCl. - By absorbing HCl, pyridine prevents the reverse reaction from occurring, which would otherwise regenerate acetyl chloride and ethyl alcohol. ### Step 5: Conclusion Thus, the function of pyridine in this reaction is to act as a base that absorbs the HCl produced, driving the reaction towards the formation of the ester and preventing any backward reaction. ### Final Answer The function of pyridine in the reaction is to absorb the liberated HCl, preventing the reverse reaction and facilitating the formation of the ester. ---
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HIMANSHU PANDEY-CABOXYLIC ACIDS AND ITS DERIVATIVES-Level 1 (Q.27 To Q.50)
  1. The compound which on reduction with LiAlH(4) gives two different alco...

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  2. Consider the following sequence of reactions identify A, B, C and...

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  3. CH(3)COCl+C(2)H(5)OH overset("Pyridine")rarr CH(3)COOC(2)H(5)+HCl Th...

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  4. CH(3)COCl react with :

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  5. The end product in the reaction is: CH(3)CONH(2)overset(P(2)O(5))rar...

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  6. Hofmam bromamide reaction involves the intermadiate formation of:

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  7. RCOOAg+Br(2)overset(C C1(4))underset(Delta)rarrR-Br+AgBr+CO(2) this re...

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  8. Main product of the reactions is : CH(2)CONH(2)+HNO(2)rarrProduct

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  9. the reaction, CH(3)COOC(2)H(5) overset(Na+C(2)H(5)OH)underset(4[H])rar...

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  10. The reaction CH(3)CONH(2) overset(NaOBr)rarr , gives:

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  11. The reaction of acetaldehyde in the presence of Al(OC(2)H(5))(3) produ...

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  12. Methyl acetate on treating with excess of C(2)H(5)MgBr produces :

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  13. In a set reaction propionic acid yielded a compound D CH(3)CH(2)COOH...

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  14. Name the end product in the following series of reaction CH(3)COOH o...

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  15. The end product in the following sequence is: "Accetamide"overset(P(...

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  16. C(6)H(5)COOCH(3)+.^(18)OH^(-)rarrA+B In the above reaction, products...

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  17. Reaction of R-overset(O)overset(||) C-NH2 with a mixture of Br2 and KO...

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  18. in which of the following reactions propionic anhydride is not obtaine...

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  19. Identify 'Z' in the reaction given below: CH(3)CHO overset(MnO(4)^(-...

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  20. Which one of the following is an example of Rosenmund's reduction ?

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