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Justify the position of lanthanides a...

Justify the position of lanthanides and actinides in the periodic table .

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(i) The actual position of Lanthanoids in the periodic table is at group number 3 and period number 6 .However in the sixth period after lanthanum , the electrons are preferentially filled in inner 4f sub shell and these fourteen elements following lanthanum show similar chemical properties. Therefore these elements are grouped together and placed at the bottom of the periodic table . This position can be justified as follows.
(a) Lanthanoids have general electronic configuratration `[Xe] 4f^(gamma -14) 5d^(0-1) 6s^(2)`
( b) The common oxidation state of lanthanoides is +3
( c ) All these elements have similar (ii) Simiilarly the fourtheen elements following actinium resemble in their physical and chemical properties .
(iii) Similar to lanthanoids activities are also placed in a separate row at the botton of the periodic table.
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SURA PUBLICATION-TRANSITION AND INNER TRANSITION ELEMENTS-Answer the Following Question
  1. Explain the oxidation states of 4d series elements.

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  2. What are inner transition elements ?

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  3. Justify the position of lanthanides and actinides in the periodic...

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  4. What are actinide ? Give three example .

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  5. Why Gd^(3+) is colourless ?

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  6. Explain why compounds of Cu^(2+) are coloured but those of Zn^(2...

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  7. (a) Describe the preparation of potassium dichromate.

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  8. What is lanthanide contraction and what are the effects of lanth...

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  9. Complete the following a . MnO(4)^(2+) + H^(+) to ? b . C(6) H(...

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  10. What are interstitial compounds ?

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  11. Calculate the number of unpaired electrons in Ti^(3+) , Mn^(2+) a...

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  12. Write the electronic configuration of Ce^(4+) and Co^(2+)

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  13. Explain briefly how +2 states becomes more and more stable in t...

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  15. Explain the variation in E(m^(2+))^(0) //M 3d series .

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  16. Compare Lantanides and actinides.

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  17. Explain why Cr^(2+) strongly reducing while Mn^(3+) is strongly ...

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