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Consider the following sequence of react...

Consider the following sequence of reactions:
`PhCO_(2)H underset(2. NH_(3))overset(1. PCk_(5))rarr A underset(2. H_(2)//Ni)overset(1. P_(4)O_(10). "heat")rarrB`. The final product (B) is:

A

benzonitrile

B

benzlamine

C

aniline

D

benzamide

Text Solution

AI Generated Solution

The correct Answer is:
To determine the final product (B) from the given sequence of reactions, let's break down the steps involved: ### Step 1: Identify the Starting Material The starting material is benzoic acid (PhCO₂H), which has the structure: ``` O || Ph-C-OH ``` ### Step 2: Reaction with Ammonia The first reaction involves treating benzoic acid with ammonia (NH₃) in the presence of phosphorus pentachloride (PCl₅). PCl₅ converts the carboxylic acid group into an amide group. The reaction can be represented as: ``` PhCO₂H + NH₃ → PhCONH₂ (Benzamide) ``` So, the product A is benzamide (PhCONH₂). ### Step 3: Reaction with P₄O₁₀ and Heat Next, benzamide (A) is heated with phosphorus pentoxide (P₄O₁₀). This reaction leads to the formation of a nitrile (in this case, benzonitrile). The reaction can be represented as: ``` PhCONH₂ + P₄O₁₀ + heat → PhC≡N (Benzonitrile) ``` ### Step 4: Hydrogenation The final step involves hydrogenating benzonitrile (PhC≡N) using hydrogen gas (H₂) in the presence of nickel (Ni) as a catalyst. This reaction converts the nitrile group into an amine group: ``` PhC≡N + H₂ → PhCH₂NH₂ (Benzylamine) ``` Thus, the final product B is benzylamine (PhCH₂NH₂). ### Final Product The final product (B) is benzylamine. ---

To determine the final product (B) from the given sequence of reactions, let's break down the steps involved: ### Step 1: Identify the Starting Material The starting material is benzoic acid (PhCO₂H), which has the structure: ``` O || Ph-C-OH ...
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