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Rusting of iron is an electrochemical ph...

Rusting of iron is an electrochemical phenomenon. Explain.

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When iron object exposed to moist air corrosion takes place. Iron being electropositive undergoes oxidation releasing electrons.
These electrons go to another spot of the metal and reduces oxygen in presence of `H^(+)`.
Reactions:
`"Anode: "2Fe^(s) to 2Fe^(2+)+4e^(-)`
`"Cathode: "O_(2)(g)+4H^(+)+4e^(-) to 2H_(2)O`
`"Overall reactions: "2Fe(s)+O_(2)(g)+4H^(+) to 2Fe^(2+)+2H_(2)O`
The ferrous ions are further oxidised by atmospheric oxygen to ferric ions which come out as rust in the form of hydrated ferric oxide. `Fe_(2)O_(3). xH_(2)O`
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(a) Most of the metals acquire a dull surface when exposed to air . Name the chemical phenomenon responsible for this process. (b) State the conditions under which the iron articles get rusted . Design an activity to investigate the conditions necessary for rusting .

Describe an activity to show that the rusting of iron occurs in the presence of air and moisture.

SUBHASH PUBLICATION-ELECTROCHEMISTRY-Problem Section
  1. Rusting of iron is an electrochemical phenomenon. Explain.

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  2. E(cu)^(0)=0.34 and E(zn)^(0)=-0.76V. Calculate E("cell")^(0).

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  3. E(Cu)^(0)=+0.34V and E(Ag)^(0)=+0.8V" calculate "E(cell")^(0).

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  4. Calculate the EMF of the cell for the reaction. Mg((s))+2Ag((aq))^+ ...

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  5. Calculate the e.m.f. of the cell in which the following reaction takes...

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  6. Represent the cell in which the following reaction takes place Mg(s)...

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  7. Calculate EMF of the cell represents below Zn//Zn^(2+)(C=0.1M)||Cu^(2+...

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  8. For the standard cell Cu(s)|Cu^(2+)(aq)||Ag^(+)(aq)|Ag(s). [E((Cu^(2+)...

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  9. For the standard cell Cu(s)|Cu^(2+)(aq)||Ag^(+)(aq)|Ag(s). [E((Cu^(2+)...

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  10. Find the value of AG^(@) at 25^(@)C for the following electrochemical ...

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  11. Calculate e.m.f. of cell for the reaction : Mg((s))+Cu^(2+)"(0.0001 ...

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  12. Calculate DeltarG^@ for the following reactions: Fe^(+2) (aq)+Ag^(+)...

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  13. Find the value of AG^(@) at 25^(@)C for the following electrochemical ...

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  14. (a) The electrode potential for the Daniell cell given below is 1.1 V....

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  15. Calculate standard free energy change for reaction Zn(S)+2Ag^(+)(aq) L...

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  16. Calculate the equilibrium constant for the reaction Cu(s)+2Ag+(aq)ra...

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  17. Calculate the equilibrium constant for the reaction Cu(s)+2Ag+(aq)ra...

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  18. The cell in which of the following reaction occurs: 2Fe^(3+)(aq)+2I^...

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  19. Resistance of a conductivity cell filled with 0.02 M KCl solution is 5...

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  20. The resistance of solution of a salt occupying a volume between two pl...

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  21. c) Resistance of a conductivity cell containing 0.1 M KCl solution is ...

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