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The major product of the following react...

The major product of the following reaction is :
`{:(CH_(3)CH_(2)CH-CH_(2) ),(" |"" |"),(" "Br" " Br):}` `underset(underset("in liq" NH_(3))(II. NaNH_(2)))overset("I. KOH alc")rarr`

A

`CH_(3)CH_(2)C -= CH`

B

`CH_(3)CH = C = CH_(2)`

C

`{:(CH_(3)CH_(2)CH-CH_(2)),(" |"" |"),(" "NH_(2)" "NH_(2)):}`

D

`CH_(3)CH=CHCH_(2)NH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction step-by-step, we will analyze the reactants and the reagents used in the reaction. The reactant is 1,2-dibromobutane, and we will go through the elimination and substitution processes to find the major product. ### Step 1: Identify the Reactant The reactant is 1,2-dibromobutane, which can be represented as: ``` CH3-CH2-CH-CH2 | | Br Br ``` ### Step 2: First Step - Dehydrohalogenation with KOH (alc) In the first step, we treat the reactant with alcoholic KOH, which provides hydroxide ions (OH⁻). This will lead to a dehydrohalogenation reaction, where one of the bromine atoms and a hydrogen atom are eliminated to form a double bond. - The hydroxide ion will preferentially remove the less hindered hydrogen atom (which is attached to the carbon adjacent to the bromine). - The elimination will result in the formation of a double bond between the second and third carbon atoms. The product after this step will be: ``` CH3-CH2-CH=CH2 | Br ``` This product is 3-bromobutene. ### Step 3: Second Step - Reaction with NaNH2 in Liquid NH3 In the second step, we introduce sodium amide (NaNH2) in liquid ammonia (NH3). Sodium amide is a strong base and will deprotonate the hydrogen atom adjacent to the double bond, leading to the formation of a carbon anion. - The carbon anion will then undergo another elimination reaction, where the bromine atom will leave, resulting in the formation of a triple bond. The final product after this step will be: ``` CH3-CH2-C≡CH ``` This compound is 1-butyne. ### Conclusion The major product of the overall reaction is 1-butyne (CH3-CH2-C≡CH). ### Final Answer The major product of the reaction is **1-butyne** (CH3-CH2-C≡CH). ---

To solve the given reaction step-by-step, we will analyze the reactants and the reagents used in the reaction. The reactant is 1,2-dibromobutane, and we will go through the elimination and substitution processes to find the major product. ### Step 1: Identify the Reactant The reactant is 1,2-dibromobutane, which can be represented as: ``` CH3-CH2-CH-CH2 | | Br Br ...
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