Home
Class 11
CHEMISTRY
Describe the bulk preparation of dihydro...

Describe the bulk preparation of dihydrogen by electrolytic method. What is the role of an electrolyte in this process?

Text Solution

Verified by Experts

Dihydrogen is prepared by the electrolysis of acidified of alkaline water using platinum electrodes. Generally, 15-20% of an acid `(H_(2)SO_(4))` or a base (NaOH) is used Reduction of water occurs at the cathode as:
`2OH^(-) to H_(2)O+(1)/(2)O_(2)+2e^(-)`
`therefore` Net reaction can be represented as:
`H_(2)O_(l) to H_(2_(s))+(1)/(2_(g))`
Electrical conductivity of pure water is ver low owing to the absence of ions in it. Therefore, electrolysis of pure water also takes at a low rate. If an electrolyte such as an acid or a base is added to the process, the rate of electrolysis increases. The addition of the electrolyte makes the ions available in the process for the conduction of electrolysis to take places.
Promotional Banner

Topper's Solved these Questions

  • HYDROGEN

    NCERT|Exercise EXERCISE|36 Videos
  • HYDROCARBONS

    NCERT|Exercise EXERCISE|25 Videos
  • ORGANIC CHEMISTRY- SOME BASIC PRINCIPLES AND TECHNIQUES

    NCERT|Exercise EXERCISE|40 Videos

Similar Questions

Explore conceptually related problems

What is an electrolyte?

Kolbe's electrolytic method can be applied on

What are blood electrolytes?

What are the charge carriers in electrolytes

NCERT-HYDROGEN-EXERCISE
  1. Why does hydrogen occur in a diatomic from rather than in a monoatomic...

    Text Solution

    |

  2. How can the production of dihydrogen, obtained from 'Coal gasification...

    Text Solution

    |

  3. Describe the bulk preparation of dihydrogen by electrolytic method. Wh...

    Text Solution

    |

  4. Complete the following reactions: a.H(2)(g)+M(m)O(o)(s)overset(Delt...

    Text Solution

    |

  5. Discuss the consequences of high enthalpy of H-H bond in terms of chem...

    Text Solution

    |

  6. What do you understand by (i) electron-deficient, (ii) electron-precis...

    Text Solution

    |

  7. What characteristics do you expect from an electron-deficient hydride ...

    Text Solution

    |

  8. Do you expect the carbon hydrides fo the type (C(n)H(2n+2)) to act as ...

    Text Solution

    |

  9. What do you understand by the term “non-stoichiometric hydrides”? Do y...

    Text Solution

    |

  10. How do you expect the metallic hydrides to be useful for hydrogen stor...

    Text Solution

    |

  11. How does the atomic hydrogen or oxy-hydrogen torch funtion for cutting...

    Text Solution

    |

  12. Among NH(3),H(2)O, and HF, which would you expect to have highest magn...

    Text Solution

    |

  13. Saline hydrides are known to react with water violently producing fire...

    Text Solution

    |

  14. Arrange the following (i) CaH(2), BeH(2) and TiH(2) in order of increa...

    Text Solution

    |

  15. Compare the stuctures of H(2)O and H(2)O(2).

    Text Solution

    |

  16. What do you understand by the term 'auto-protolysis' of water? What is...

    Text Solution

    |

  17. Consider the reacton of water with F(2) and suggest, in terms of oxida...

    Text Solution

    |

  18. Complete the following chemical reactions. (i) PbS(s)+H(2)O(2)(aq) t...

    Text Solution

    |

  19. Describe the structure of the common form of ice.

    Text Solution

    |

  20. What causes the temporary and permanent hardness of water ?

    Text Solution

    |