Home
Class 12
CHEMISTRY
The reaction Cr2O3+2AltoAl2O3+2Cr (tri...

The reaction
`Cr_2O_3+2AltoAl_2O_3+2Cr` `(triangleG^(ɵ)=-421kJ))`
Is thermodynamically feasible as is apparent from the Gibbs energy value. Why does it not take place at room temperature?

Text Solution

Verified by Experts

The correct Answer is:
Certain amount of activation energy is essential even for such reactions which are thermodynamically feasible, therefore heating is required.

this is explained on the basis of `K_(eq)` the equilibrium constant in the given redox reaction , all reactants and products and Hence the reactions does not ovcure sat RT At High temparture Cr Melt and values of TAS increase As a result the value of
`Delta _(t)G^(Theta)` Becomes more nagative an hence the reaction procedds rapidly .
Promotional Banner

Topper's Solved these Questions

  • GENERAL PRINCIPLES AND PROCESSESS OF ISOLATION OF ELEMENTS

    NCERT|Exercise Exercise|31 Videos
  • ELECTROCHEMISTRY

    NCERT|Exercise Exercise|33 Videos
  • HALOALKANES AND HALOARENES

    NCERT|Exercise EXERCISE|31 Videos

Similar Questions

Explore conceptually related problems

Give reason : Reduction of Cr_(2) O_(3) with Al is thermodynamically feasible, yet it does no occur at room temperature.

(A) The reduction reaction, Cr_(2)O_(3)+2Al to Al_(2)O_(3)+2Cr, DeltaG^(0)=-421KJ is not possible at room temperature (R ) Certain amount of activation energy is essential for the reaction to make it thermodynamically feasible.

In the reaction: 2Al + Cr_(2) O_(3) rarr Al_(2) O_(3) + 2 Cr , 4.98 g of Al reacted with 20.0 g Cr_(2)O_(3) . How much grams of reactant ramains at the completion of the reaction?

In Cr_2O_7^(2-) all Cr-O bonds are equivalent.

NCERT-GENERAL PRINCIPLES AND PROCESSESS OF ISOLATION OF ELEMENTS -Exercise
  1. Which of the ores mentioned in Table 6.1 can be concentrated by magnet...

    Text Solution

    |

  2. What is the significance of leaching in the extraction of aluminium?

    Text Solution

    |

  3. The reaction Cr2O3+2AltoAl2O3+2Cr (triangleG^(ɵ)=-421kJ)) Is therm...

    Text Solution

    |

  4. It is true that under certain condition, Mg can reduce Al2O3 and Al ca...

    Text Solution

    |

  5. Copper can be extracted by hydrometallurgy but not zinc because

    Text Solution

    |

  6. What is the role of depressant in froth floatation process?

    Text Solution

    |

  7. Why is the extraction of copper from pyrites more difficult than that ...

    Text Solution

    |

  8. Explain: (i). Zone refining (ii). Column chromatography.

    Text Solution

    |

  9. Out of C and CO, which is a better reducing agent at 673K?

    Text Solution

    |

  10. Name the common elements present in the anode mud in electrolytic refi...

    Text Solution

    |

  11. Write down the reactions taking place in different zones in the blast ...

    Text Solution

    |

  12. Write down the chemical reactions taking place in the extraction of zi...

    Text Solution

    |

  13. State the role of silica in the metallurgy of copper.

    Text Solution

    |

  14. Which method of refining may be more suitable if element is obtained i...

    Text Solution

    |

  15. Which method of refining will you suggest for an element in which impu...

    Text Solution

    |

  16. Describe a method for refining nickel.

    Text Solution

    |

  17. How can you separate alumina from silica in a bauxite ore associated w...

    Text Solution

    |

  18. Giving examples differentiate between roasting and calcination.

    Text Solution

    |

  19. How is ‘cast iron’ different from ‘pig iron”?

    Text Solution

    |

  20. Differentiate between “minerals” and “ores”.

    Text Solution

    |