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How would you determine the standard reduction potential of the system `Mg^(2+)|Mg`?

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A cell will be set up consisting of `Mg//MgSO_(4)(1M)` as one electrode and standard hydrogen electrode Pt, H, (1atm) `H^(+)//(1M)` as second electrode, measure the EMF of the cell and also note the direction of deflection in the voltmeter. The direction of deflection shows that `e^(-1)` s flow from mg electrode to hydrogen electrode, i.e., oxidation takes place on magnesium electrode and reductio on hydrogen electrode. Hence, the cell may be represetned as follows.
`Mg|Mg^(2+)(1M)||H^(+)(1M)|H_(2),(1atm),Pt`
`E_(Cell)^(@)=E_(H^(+)//(1)/(2)H_(2))^(@)-E_(Mg^(2+)//Mg)^(@)`
Put `E_(H^(+)//(1)/(2)H_(2))^(@)=0`
`thereforeE_(Mg^(2+)//Mg)^(@)=-E_(cell)^(@)`
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Knowledge Check

  • Standard reduction potential is calculated at

    A
    `27^(@)C`
    B
    `25^(@)C`
    C
    `0^(@)C`
    D
    `100^(@)C`
  • Standard reduction potential of an element equal to

    A
    `+ 1 xx` its reduction potential
    B
    `- 1 xx ` its standard oxidation potential
    C
    `0.00`V
    D
    `+ 1 xx ` its standard oxidation potential
  • The first ionization potential of Mg is

    A
    less than Al
    B
    more than Al
    C
    equal to Al
    D
    can be less or more than Al
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