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Why is the extraction of copper from pyr...

Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?

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`Delta _(f) G^(@)` of `Cu_(2)s` is more negative than `Delta _(f) G^(@)` of `Cs_(2)` and `H_(2) S` So `Cu_(2)S` can not be reduced by carbon or hydrogen `Delta_(f)G^(@)`of `Cu_(2)O so `CU_(2) O can be reduced by carbon . So pyrites is first converrted to oxide before reducation to copper
`Cu_(2) S(s) +(3)/(2) O_(2) (g) to CU_(2) O (s) +So_(2)(g) `
` Cu_92)O(s) +C(s) to 2Cu (s) +CO(s)`
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NCERT-GENERAL PRINCIPLES AND PROCESSESS OF ISOLATION OF ELEMENTS -Exercise
  1. Copper can be extracted by hydrometallurgy but not zinc because

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  2. What is the role of depressant in froth floatation process?

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  3. Why is the extraction of copper from pyrites more difficult than that ...

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  4. Explain: (i). Zone refining (ii). Column chromatography.

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  5. Out of C and CO, which is a better reducing agent at 673K?

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  6. Name the common elements present in the anode mud in electrolytic refi...

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  7. Write down the reactions taking place in different zones in the blast ...

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  8. Write down the chemical reactions taking place in the extraction of zi...

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  9. State the role of silica in the metallurgy of copper.

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  10. Which method of refining may be more suitable if element is obtained i...

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  11. Which method of refining will you suggest for an element in which impu...

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  12. Describe a method for refining nickel.

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  13. How can you separate alumina from silica in a bauxite ore associated w...

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  14. Giving examples differentiate between roasting and calcination.

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  15. How is ‘cast iron’ different from ‘pig iron”?

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  16. Differentiate between “minerals” and “ores”.

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  17. Why copper matte is put in silica lined converter?

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  18. What is the role of cryolite in the metallurgy of aluminium?

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  19. How is leaching carried out in case of low grade copper ores?

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  20. Why is zinc not extracted from zinc oxide through reduction using CO?

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