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The choice of a reducing agent in a part...

The choice of a reducing agent in a particular case depends on thermodynamic factor. How far do you agree with this statement ? Support your opinion with example.

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we can study the chioe of a reducing agent paticular case using ellingham digram , it is evident from th diagram that metals for which the standard free energy of formation oftheir oxides is more nagative can redue those metal oxides for which the standard free energy of formataion of their erespective oxides is less nagative it means that any metal will reduce the oxides of other metals which lie above itin the Elingham digam this is because the standar free energy change `(Delta _(r)G^(@))` of the combined redox eraction will be neagative by an amount equal to the difference in `Delta _(f)G^(@)` of the metal oxides thus both AL and Zn can reduce FeO to Fe but Fe cannot reduce `Al_(2)O_(3)` to Al an dZnP to Zn in the same way ,G can reduce An O to Zn but not CO.
Note:- Only that reagent will be preferred as reducing agent which lead to decocase i free energy value `(DeltaG^(@))` at a cetsin specific temperature .
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NCERT-GENERAL PRINCIPLES AND PROCESSESS OF ISOLATION OF ELEMENTS -Exercise
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  2. State the role of silica in the metallurgy of copper.

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  3. Which method of refining may be more suitable if element is obtained i...

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  4. Which method of refining will you suggest for an element in which impu...

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  5. Describe a method for refining nickel.

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  6. How can you separate alumina from silica in a bauxite ore associated w...

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  7. Giving examples differentiate between roasting and calcination.

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  8. How is ‘cast iron’ different from ‘pig iron”?

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  9. Differentiate between “minerals” and “ores”.

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  10. Why copper matte is put in silica lined converter?

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  11. What is the role of cryolite in the metallurgy of aluminium?

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  12. How is leaching carried out in case of low grade copper ores?

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  13. Why is zinc not extracted from zinc oxide through reduction using CO?

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  14. The value ofDelta (f) f^(Ө) for formation of Cr(2) O(3) is – 540 kJmol...

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  15. Out of C and CO, which is better reducing agent for ZnO?

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  16. The choice of a reducing agent in a particular case depends on thermod...

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  17. Name the processes from which chlorine is obtained as a by-product. Wh...

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  18. What is the role of graphite rod in the electrometallurgy of aluminium...

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  19. Outline the principles of refining of metals by the following methods ...

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  20. Predict conditions under which Al might be expected to reduce MgO.

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