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Why following two reaction proceed diffe...

Why following two reaction proceed differently?
`Pb_(3)O_(4)+8HClrarr3PbCl_(2)+Cl_(2)+4H_(2)O`
and
`Pb_(3)O_(4)+4HNO_(3)rarr2Pb(NO_(3))_(2)+PbO_(2)+2H_(2)O`

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`Pb_(3)O_(4)` is actually a stoichiometric mixture of 2 mol of PbO and 1 mol of `PbO_(2)`. In `PbO_(2)`, lead is present in +4 oxidation state, whereas the stable oxidation state of lead in PbO is +2. `PbO_(2)` thus can act as an oxidant (oxidising agent) and, therefore, can oxidise Cl– ion of HCl into chlorine. We may also keep in mind that PbO is a basic oxide. Therefore, the reaction
`Pb_(3)O_(4) + 8HCl to 3 PbCl_(2) + Cl_(2) + 4 H_(2)O` can be splitted into two reactions namely :
`2PbO + 4 HCl to 2 PbCl_(2) + 2H_(2)O` (acid -base reaction)
`overset(4+)(Pb)O_(2) + 4 Hoverset(-1)(Cl) to overset(+2)(Pb)Cl_(2) + overset(0)(Cl_(2)) underset("redox reaction")(2H_(2)O)`
Since `HNO_(3)` itself is an oxidising agent therefore, it is unlikely that the reaction may occur between `PbO_(2)` and `HNO_(3)`. However, the acid-base reaction occurs between PbO and `HNO_(3)` as :
`2PbO + 4 HNO_(3) to 2 Pb (NO_(3))_(2) + 2H_(2)O`
It is the passive nature of `PbO_(2)` against `HNO_(3)` that makes the reaction different from the one that follows with HCl.
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Why following two reaction proced differently? Pb_(3)O_(4)+8HClrarr3PbCl_(2)+Cl_(2)+4H_(2)O and Pb_(3)O_(4)+4HNO_(3)rarr2Pb(NO_(3))_(2)+PbO_(2)+2H_(2)O

What is redox reaction? Identify the substance oxidised and the substance reduced in the following reactions. (a) Pb_(3)O_(4)+8HClrarr3PbCl_(2)+Cl_(2)+4H_(2)O (b) CuO+H_(2)rarrCu+H_(2)O (b) CuO+H_(2)rarrCu+H_(2)O

Pb(NO_(3))_(2)+H_(2)SO_(4) to PbSO_(4)darr+2HNO_(3)

Pb_(3)O_(4)+HNO_(3)(dil.) overset(R.T.) to Pb(NO_(3))_(2)+PbO_(2)darr

PbO_(2)+HNO_(3)("Conc.") to Pb(NO_(3))_(2)+H_(2)O+[O]

NCERT-REDOX REACTIONS-EXERCISE
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  4. Justify that the following reaction are redox reactions: a. CuO(s)+H...

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  5. Fluorine reacts with ice and results in the change: H(2)O(s)+F(2)(g)...

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  7. Write formulas for the following compounds: a. Mercury (II) chloride...

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  8. Suggest a list of the substances where carbon can exhibit oxidation st...

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  9. While sulphate dioxide and hydrogen peroxide can act as oxidising as w...

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  10. Consider the reaction: a. 6CO(2)(g)+6H(2)O(l)rarr C(6)H(12)O(6)(aq)+...

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  11. The compound AgF(2) is an unstable compound. However, if formed, the c...

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  12. Whenever a reaction between an oxidising agent and a reducing agent is...

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  13. How do you count for the following observations ? (a) Though alkali...

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  14. Identify the substance oxidised substance reduced, oxidising agent, an...

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  15. Consider the reaction: 2S(2)O(3)^(2-)(aq)+I(2)(s) rarr S(4)O(6)^(2-)...

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  16. Justify giving reaction that among halogens, fluorine is the best oxid...

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  17. Why does the following reaction occur? XeO(6)^(4-)(aq)+2F^(Θ)(aq)+6H...

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  18. Consider the reactions: a. H(3)PO(2)(aq)+4AgNO(3)(aq)+2H(2)O(l) rarr...

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  19. Balance the following redox reactions by ion electron method: a. MnO...

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  20. Balance the following equations in basic medium by ion-electron method...

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  21. What sort of informations can you draw from the following reaction? ...

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