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(D) & (L) configuration of above carbohy...


(D) & (L) configuration of above carbohydrate is :

A

L,L,D

B

L,D,L

C

L,L,L

D

L,D,D

Text Solution

Verified by Experts

The correct Answer is:
b


D and L notations can be used to describe the configuration of corbohydrates and amino acids, so it is important to learn what D and L. signify. In Fischer projections of monosaccharides, the carbonyl group is always placed on top ( in the case of aldoses) or as close to the top as possible (in hte case of ketoses). From its structure, you can see that galactose has four chirlity centers (C-2, C-3, C-4, and C-5). If the OH group attached to the bottom-most chiralirty center (the second from the left, the compound is and L-sugar. Almost all sugars found in nature are D-sugars. Notice that the mirror image of a D-sugar is an L-sugar.

D nad L, like R and S, indicate the configuration of a chirality center, but they do not indicate whether the compound rotates plane-polarized light to the right (+) or levorotatory. In other words, optical rotation, like melting or boiling points, is a physical property of a compound, whereas "R,S, D and L" are convertions humans use to depict the structure of the molecule.
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Specify the configuration of the following compounds in D or L designation. (a) Strategy: The sterochemicla descriptor D refers to an arrangement about a centre of chirality that is identical to the three-dimensional arrangement in D-(+)- glyceraldehyde in which the OH group on the chiral centre is on the right in the Fischer projection. Similarly, the other enatiomer of glyceraldehyde, which has _OH group on the chiral centre to the left is given L configuration. For carbohydrates (polyhdroxy aldehydes or ketones) the focus should be on the last chiral carbon (from the top) while for amino acids the focus should be on the chiral carbon carrying the NH_(2) group.