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The correct stability order of the follo...

The correct stability order of the following resonance structures is :
x`H_(2)C=overset(o+)underset((I))N=overset(Ɵ)N`
`H_(2)overset(o+)Cunderset((II))-N=overset(Ɵ)N`
`H_(2)overset(Ɵ)C-underset((III))overset(o+)N-=N`
`H_(2)overset(Ɵ)C-underset((IV))N=overset(o+)N`

A

`IgtIIgtIVgtIII`

B

`IgtIIIgtIIgtIV`

C

`IIgtIgtIIIgtIV`

D

`IIIgtIgtIVgtII`

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The correct Answer is:
To determine the stability order of the given resonance structures, we need to analyze each structure based on the octet rule and the placement of charges. Here’s a step-by-step breakdown of the analysis: ### Step 1: Analyze Each Resonance Structure 1. **Structure I**: \( H_2C = N^+ - N^- \) - Carbon has 4 bonds (2 from H and 2 from N), fulfilling the octet rule. - Nitrogen \( N^+ \) has 6 electrons (3 bonds), and \( N^- \) has 8 electrons (4 bonds). - Overall, all atoms have complete octets. 2. **Structure II**: \( H_2C^+ - N = N^- \) - Carbon has 3 bonds (2 from H and 1 from N), which means it has only 6 electrons (not fulfilling the octet rule). - The nitrogen \( N^- \) has 8 electrons (4 bonds), while the other nitrogen has 6 electrons (3 bonds). - This structure is less stable due to carbon not fulfilling the octet. 3. **Structure III**: \( H_2C - N \equiv N^+ \) - Carbon has 4 bonds (2 from H and 2 from N), fulfilling the octet rule. - The terminal nitrogen \( N^+ \) has 6 electrons (3 bonds), while the other nitrogen has 8 electrons (4 bonds). - This structure is stable as carbon fulfills the octet. 4. **Structure IV**: \( H_2C - N = N^+ \) - Carbon has 4 bonds (2 from H and 2 from N), fulfilling the octet rule. - The nitrogen \( N^+ \) has 6 electrons (3 bonds), while the other nitrogen has 8 electrons (4 bonds). - This structure is stable, but one nitrogen has a positive charge. ### Step 2: Evaluate Stability Based on Octet Rule and Charge Distribution - Structures that fulfill the octet rule are generally more stable. - Positive charges should ideally be on less electronegative atoms, while negative charges should be on more electronegative atoms. ### Step 3: Compare the Structures - **Structure I** is stable with all atoms fulfilling the octet rule and has a positive charge on nitrogen (more electronegative). - **Structure III** is also stable with fulfilled octets but has a positive charge on nitrogen. - **Structure IV** has fulfilled octets but has a positive charge on nitrogen. - **Structure II** is the least stable as carbon does not fulfill the octet rule. ### Conclusion: Stability Order Based on the analysis: 1. Structure I: \( H_2C = N^+ - N^- \) (most stable) 2. Structure III: \( H_2C - N \equiv N^+ \) 3. Structure IV: \( H_2C - N = N^+ \) 4. Structure II: \( H_2C^+ - N = N^- \) (least stable) Thus, the correct stability order is: **I > III > IV > II**

To determine the stability order of the given resonance structures, we need to analyze each structure based on the octet rule and the placement of charges. Here’s a step-by-step breakdown of the analysis: ### Step 1: Analyze Each Resonance Structure 1. **Structure I**: \( H_2C = N^+ - N^- \) - Carbon has 4 bonds (2 from H and 2 from N), fulfilling the octet rule. - Nitrogen \( N^+ \) has 6 electrons (3 bonds), and \( N^- \) has 8 electrons (4 bonds). - Overall, all atoms have complete octets. ...
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The correct stability order of the following resonance structures is (I)H_(2)C = overset(+)N = overset(-)N" "(II)H_(2)overset(+)C - N = overset(-)N (III)H_(2)overset(-)C - overset(+)N = N" "(IV)H_(2)overset(-)C - N = overset(+)N

The correct stability order of the following resonance structure is: {:(CH_(2)=C=O,H_(2)overset(-)(C)-overset(+)(C)=O,H_(2)O=overset(+)(C)-overset(-)(O) , H_(2)overset(-)(C)-C-=O),((I),(II),(III),"(IV)"):}

Give the stability of the following resonance structures (a) H_(2)C = overset(o+)N =overset(Θ) (b) H_(2)overset(o+)C -N =overset(Θ)N (c ) H_(2)overset(Θ)C -overset(o+)N -= N (d) H_(2) overset(Θ)C - N = overset(o+)N .

The correct order of stabilities of the following resonance structures is : (I) H_2 C = overset (oplus) N = overset (Ө) N (II) H_2 overset (oplus) C - N = overset (Ө) N (III) H_2 overset (Ө) C - overset (oplus) N -= N (IV) H_2 overset (Ө) C - N = overset (oplus) N .

The correct stability order of the following resonance structrue is : H_2 C = overset (+)(N) = overline(N) H_2 overset (+)C = (N) = overline(N) H_2overline( C) - overset (+) (N) -= N H_2overline( C) - overset (+) (N) -= N .

For hydrazoic acid, which of the following resonating structure well be least stable? underset("(I)")(H-N=overset(+)N=overset(-)N)harrunderset(" (II)")(H-overset(+)N-overset(+)N=N^(2-))harrunderset("(III)")(H-overset(-)N-overset(+)N-=N)

HIMANSHU PANDEY-GENERAL ORGANIC CHEMISTRY-Level 2 (Q.26 To Q.50)
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  2. In which of the following molecules pi-electron density in ring is max...

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  3. The correct stability order of the following resonance structures is :...

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  4. What is correct increasing oreder of bond lengths of bond indicated as...

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  5. Acylium cation has two resonating sturctures (I) and (II), R-underse...

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  6. Consider the following three amines, (1) CH(3)CH(2)-overset(* *)NH(2...

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  7. The C-Cl bond length is shortest in :

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  8. Which of the following pairs of structure are resonance structure?

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  9. Which of the following is pair of resonance structure?

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  10. The most stable diene is :

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  11. Which of the following cation would have greatest stability?

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  12. Which of the following is not valid resonance structre of polyene?

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  13. Most contributing structure in introethene is :

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  14. The most stable resonating structure of CH(3)-underset(* *)overset(* ...

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  15. Which of the following does not represent structure of ?

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  16. The correct stability order of following species is :

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  17. Choose the correct staement :

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  18. Which carbocation is most stabilised among following?

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  19. Which of the following cations is most stable?

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  20. Which of the following cations is most stable?

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