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Compare the chemistry of actinoids with ...

Compare the chemistry of actinoids with that of the lanthanoids with special reference to:
(i) Electronic configuration
(ii) Oxidation states
(iii) Chemical reactivity

Text Solution

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Electronic configuration
The general electronic configuration for lanthanoids is `[Xe]^(54) 4f^(0-14) 5d^(0-1) 6s^(2)` and that for actinoids is `[Rn]^(86) 5f^(1-14) 6d^(0-1) 7s^(2)`. Unlike 4f orbitals, 5f orbitals are not deeply buried and participate in bonding to a greater extent.
Oxidation states
The principal oxidation state of lanthanoids is (+3). However, sometimes we also encounter oxidation states of + 2 and + 4. This is because of extra stability of fully-filled and half-filled orbitals. Actinoids exhibit a greater range of oxidation states. This is because the 5f, 6d, and 7s levels are of comparable energies. Again, (+3) is the principal oxidation state for actinoids. Actinoids such as lanthanoids have more compounds in +3 state than in +4 state.
Chemical reactivity
In the lanthanide series, the earlier members of the series are more reactive. They have reactivity that is comparable to Ca. With an increase in the atomic number, the lanthanides start behaving similar to Al. Actinoids, on the other hand, are highly reactive metals, especially when they are finely divided. When they are added to boiling water, they give a mixture of oxide and hydride. Actinoids combine with most of the non-metals at moderate temperatures. Alkalies have no action on these actinoids. In case of acids, they are slightly affected by nitric acid (because of the formation of a protective oxide layer).
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(a) Write the structure of Cr_2O_7^(2-) Give two uses of K_2Cr_2O_7 . (b) Write note on interstitial compounds. (c) Compare the chemistry of actinoids with that of lanthanoids with special reference to: (i) Atomic sizes (ii) Chemical reactivity.

Oxidation State And Chemical Reactivity

Oxidation State And Chemical Reactivity

Compare lanthanoids and actinoids with reference to : (i) the electronic of atoms (ii) the oxidation states of elements (iii) general chemical reactivity of elements.

NCERT-THE D AND F BLOCK ELEMENTS-Exercise
  1. Compare the stability of +2 oxidation state for the elements of the fi...

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  2. Compare the chemistry of actinoids with that of the lanthanoids with s...

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  3. How would you account for the following: A) Of the d^(4) species Cr^(...

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  4. What is meant by 'disproportionation'? Give two examples of disproport...

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  5. Which metal in the first series of transition metals exhibits +1 oxida...

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  6. Calculate the number of unpaired electrons in the following gaseous io...

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  7. Give examples and suggest reason for the following features of the tra...

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  8. Indicate the steps in the preparation of: (i). K2Cr2O7 from chromite...

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  9. What are alloys? Name an important alloy which contains some of the la...

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  10. What are inner-transition elements? Decide which of the following atom...

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  11. The chemistry of the actinoid elements is not so smooth as that of the...

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  12. Which is the last element in the series of the actinods? Write the ele...

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  13. Use Hund's rule to derive the electronic configuration of Ce^(3+) ion,...

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  14. Name the member of the lanthanoids series which exhibit +4 oxidation s...

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  15. Compare the chemistry of actinoids with that of the lanthanoids with s...

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  16. Write the electronic configuration of the elements with the atomic num...

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  17. Compare the general characteristics of the first series of the transit...

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  18. Write down the number of 3d electrons in each of the following ions: T...

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  19. Comments on the statement that elements of the first transition serie...

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  20. What can be inferred from the magnetic moment values of the following ...

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