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Estimate the fraction of molecular volum...

Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be `3 Å`.

Text Solution

Verified by Experts

Diameter of an oxygen molecule ,d=3 Å
Raidus `=(d)/(2)=(3)/(2)`
`= 1.5 Å = 1.5 × 10_(–8)` cm
Actual volume occupied by 1 mole of oxygen gas at STP = `22400 cm^3`
` V=(4)/(3) pir^(3).N` Molecular volume of oxygen gas ,
Where ,N is Avogadro's number `=6.023xx10^23` molecules /mole
`therefor V =(4)/(3)xx3.14xx(1.5xx10^-8)^3xx6.023xx10^23=8.51 cm^3`
Ratio of the molecular volume to the actual volume of oxygen` =(8.51)/(22400)`
`=3.8xx10^-4`
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Knowledge Check

  • 1 L oxygen gas at STP will weigh

    A
    1.43 g
    B
    2.24 g
    C
    11.2 g
    D
    22.4 g
  • The diameter of an oxygen molecule is 3 Ã… The ratio of molecular volume to the actual volume occupied by the oxygen gas at STP is

    A
    `2xx10^(-4)`
    B
    `1xx10^(-4)`
    C
    `1.5xx10^(-4)`
    D
    `4xx10^(-4)`
  • The maximum volume at STP is occupied by

    A
    `12.8` gram `SO_(2)`
    B
    `0.5` mole of `NO_(2)`
    C
    `6.023xx10^(22) "molecules of" CH_(4)`
    D
    `1 "gram molecules of" CO_(2)`
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